Crystal structure of 1,1′-(pyridine-2,6-diyl)bis[N-(pyridin-2-ylmethyl)methanaminium] dichloride dihydrate

被引：0
|
作者：
Merabet, Layachi [1 ,2 ]
Tasse, Marine [1 ]
Mallet-Ladeira, Sonia [1 ,3 ]
Kaboub, Lakhemici [2 ]
Malfant, Isabelle [1 ]
机构：
[1] UPR CNRS 8241, Lab Chim Coordinat, 205 Route Narbonne, F-31077 Toulouse, France
[2] Univ Ferhat Abbas Setif 1, Lab Chem Mol Engn & Nanostruct, Dept Chem, Fac Sci, Setif 19000, Algeria
[3] Inst Chim Toulouse UAR CNRS 2599, 118 Route Narbonne, F-31062 Toulouse 09, France
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2021年 / 77卷
关键词：
crystal structure; hydrogen bonding; pi-pi interactions; CARBOXAMIDE LIGANDS; RUTHENIUM NITROSYL; NO; DELIVERY; LIGHT; NITROGEN;
D O I：
10.1107/S205698902101183X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, C19H23N52+center dot 2Cl(-)center dot 2H(2)O, the two pyridine side arms are not coplanar, with the terminal pyridine rings subtending a dihedral angle of 26.45 (6)degrees. In the crystal, hydrogen bonds, intermolecular C-H center dot center dot center dot Cl contacts and a weak C-H center dot center dot center dot O interaction connect the molecule with neighbouring chloride counter-anions and lattice water molecules. The crystal packing also features by pi-pi interactions with centroid-centroid distances of 3.4864 (12) and 3.5129 (13) angstrom.
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收藏
页码：1296 / +
页数：8
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