Effect of the polymer glass transition on the chromatographic retention volumes

被引：0

作者：

Vrentas, JS ^{[1
]}

Vrentas, CM ^{[1
]}

机构：

[1] Penn State Univ, Dept Chem Engn, University Pk, PA 16802 USA

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2005年 / 97卷 / 03期

关键词：

chromatography; diffusion; glass transition; theory;

D O I：

10.1002/app.21680

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Theoretical developments are presented that explain four experimental observations concerning the temperature dependence of chromatographic specific retention volumes. A theoretical framework is proposed for a method that can be used to determine the glass-transition temperature of the pure polymer and for a method of characterizing the concentration dependence of the glass-transition temperature of a polymer-solvent system. (c) 2005 Wiley Periodicals, Inc.

引用

页码：793 / 796

页数：4

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