Effect of the polymer glass transition on the chromatographic retention volumes

被引：0
|
作者：
Vrentas, JS [1 ]
Vrentas, CM [1 ]
机构：
[1] Penn State Univ, Dept Chem Engn, University Pk, PA 16802 USA
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2005年 / 97卷 / 03期
关键词：
chromatography; diffusion; glass transition; theory;
D O I：
10.1002/app.21680
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Theoretical developments are presented that explain four experimental observations concerning the temperature dependence of chromatographic specific retention volumes. A theoretical framework is proposed for a method that can be used to determine the glass-transition temperature of the pure polymer and for a method of characterizing the concentration dependence of the glass-transition temperature of a polymer-solvent system. (c) 2005 Wiley Periodicals, Inc.
引用
收藏
页码：793 / 796
页数：4
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