The rhodium-catalyzed Pauson-Khand reaction

被引：141
|
作者：
Kobayashi, T [1 ]
Koga, Y [1 ]
Narasaka, K [1 ]
机构：
[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 624卷 / 1-2期
关键词：
Pauson-Khand reaction; rhodium; catalytic reaction; cyclopentenone;
D O I：
10.1016/S0022-328X(00)00835-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A rhodium carbonyl complex, [RhCl(CO)(2)](2), serves as a catalyst of the intra- and inter-molecular Pauson-Khand reaction. By the use of the rhodium catalyst, cyclopentenone derivatives are prepared from various 1,6- and 1,7-enynes under 1 arm of CO. Furthermore, this rhodium-catalyzed reaction is accelerated by reducing partial pressure of CO to less than 1 atm. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：73 / 87
页数：15
相关论文
共 50 条
  • [31] Diastereoselectlve Pauson-Khand reaction catalyzed by Rh: A computational study
    Wang, HJ
    Baik, MH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U2102 - U2102
  • [32] Cobalt-phosphite-catalyzed asymmetric Pauson-Khand reaction
    Sturla, SJ
    Buchwald, SL
    JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (10): : 3398 - 3403
  • [33] Rhodium-catalyzed tandem Pauson-Khand type reactions of 1,4-enynes tethered by a cyclopropyl group
    Chen, Gen-Qiang
    Shi, Min
    CHEMICAL COMMUNICATIONS, 2013, 49 (07) : 698 - 700
  • [34] The interrupted Pauson-Khand reaction.
    Krafft, ME
    Wilson, AM
    Dasse, O
    Shao, B
    Cheung, YY
    Fu, P
    Bonaga, L
    Mollman, M
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 481 - ORGN
  • [35] Cobalt nanoparticles on charcoal: A versatile catalyst in the Pauson-Khand reaction, hydrogenation, and the reductive Pauson-Khand reaction
    Son, SU
    Park, KH
    Chung, YK
    ORGANIC LETTERS, 2002, 4 (22) : 3983 - 3986
  • [36] Asymmetric Pauson-Khand reactions catalyzed by NHSG encapsulated rhodium complexes.
    Park, KH
    Chung, YK
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U1060 - U1060
  • [37] Amine induced Pauson-Khand reaction
    Tetrahedron Lett, 1-2 (117):
  • [38] Intermolecular dienyl Pauson-Khand reaction
    Wender, PA
    Deschamps, NM
    Williams, TT
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (23) : 3076 - 3079
  • [39] Rhodium-Catalyzed Pauson-Khand-Type Reaction Using Alcohol as a Source of Carbon Monoxide
    Park, Ji Hoon
    Cho, Yoonhee
    Chung, Young Keun
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (30) : 5138 - 5141
  • [40] New developments in the Pauson-Khand reaction
    Geis, O
    Schmalz, HG
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998, 37 (07) : 911 - 914
12345