The rhodium-catalyzed Pauson-Khand reaction

被引：141

作者：

Kobayashi, T ^{[1
]}

Koga, Y ^{[1
]}

Narasaka, K ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 624卷 / 1-2期

关键词：

Pauson-Khand reaction; rhodium; catalytic reaction; cyclopentenone;

D O I：

10.1016/S0022-328X(00)00835-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A rhodium carbonyl complex, [RhCl(CO)(2)](2), serves as a catalyst of the intra- and inter-molecular Pauson-Khand reaction. By the use of the rhodium catalyst, cyclopentenone derivatives are prepared from various 1,6- and 1,7-enynes under 1 arm of CO. Furthermore, this rhodium-catalyzed reaction is accelerated by reducing partial pressure of CO to less than 1 atm. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：73 / 87

页数：15

共 50 条

[21] The intermolecular Pauson-Khand reaction
Gibson, SE
Mainolfi, N
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (20) : 3022 - 3037
[22] The Tandem Pauson-Khand Reaction
Helv Chim Acta, 2 (461):
[23] An enantiospecific Pauson-Khand reaction
Fletcher, AJ
Rutherford, DT
Christie, SDR
SYNLETT, 2000, (07) : 1040 - 1042
[24] The interrupted Pauson-Khand reaction
Krafft, ME
Wilson, AM
Dasse, OA
Shao, B
Cheung, YY
Fu, Z
Bonaga, LVR
Mollman, MK
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (25) : 6080 - 6081
[25] The dienyl Pauson-Khand reaction
Wender, PA
Deschamps, NM
Gamber, GG
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (16) : 1853 - 1857
[26] The tandem Pauson-Khand reaction
Thommen, M
Veretenov, AL
GuidettiGrept, R
Keese, R
HELVETICA CHIMICA ACTA, 1996, 79 (02) : 461 - 476
[27] THE DIRECTED PAUSON-KHAND REACTION
KRAFFT, ME
JULIANO, CA
SCOTT, IL
WRIGHT, C
MCEACHIN, MD
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (05) : 1693 - 1703
[28] Interrupted Pauson-Khand reaction
Krafft, M.E.
Wilson, A.M.
Dasse, O.A.
Shao, B.
Cheung, Y.Y.
Fu, Z.
Bonaga, L.V.R.
Mollman, M.K.
Journal of the American Chemical Society, 1996, 118 (25):
[29] Rhodium-catalyzed intramolecular alkyne-carbodiimide Pauson-Khand-type reaction
Saito, Takao
Sugizaki, Katsuya
Otani, Takashi
Suyama, Toshiyuki
ORGANIC LETTERS, 2007, 9 (07) : 1239 - 1241
[30] First ruthenium-catalyzed intramolecular Pauson-Khand reaction
Kondo, T
Suzuki, N
Okada, T
Mitsudo, T
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (26) : 6187 - 6188

← 1 2 3 4 5 →