Oxo/imido heterometathesis: From molecular stoichiometric studies to well-defined heterogeneous catalysts

被引：9

作者：

Zhizhko, Pavel A. ^{[1
]}

Bushkov, Nikolai S. ^{[1
,2
]}

Pichugov, Andrey, V ^{[1
,3
]}

Zarubin, Dmitry N. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilov Str 28, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Vorobevy Gory 1, Moscow 119991, Russia

[3] D Mendeleev Univ Chem Technol Russia, Higher Chem Coll, Miusskaya Sq 9, Moscow 125047, Russia

来源：

COORDINATION CHEMISTRY REVIEWS | 2021年 / 448卷

基金：

俄罗斯科学基金会;

关键词：

Imido; Oxo; Metathesis; Heterometathesis; Cycloaddition; Surface Organometallic Chemistry; SURFACE ORGANOMETALLIC CHEMISTRY; TRANSITION-METAL-COMPLEXES; TITANIUM IMIDO COMPLEXES; SOLID-STATE NMR; OLEFIN-METATHESIS CATALYSTS; 2+2 CYCLOADDITION REACTIONS; CARBON-DIOXIDE ACTIVATION; HYDROGEN BOND ACTIVATION; NITROGEN-ATOM EXCHANGE; C-H ACTIVATION;

D O I：

10.1016/j.ccr.2021.214112

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxo/imido heterometathesis is a class of reactions that interconvert terminal transition metal oxo and imido complexes via [2 + 2] cycloaddition/cycloreversion with heteroolefins and heterocumulenes containing oxo and imino groups. In this review we summarize the literature examples of stoichiometric oxo/imido heterometathesis reactions of imido complexes with different oxo substrates and discuss the current progress in the development of catalytic oxo/imido heterometathesis. In particular, we show how application of Surface Organometallic Chemistry approach allows preparation of highly efficient oxo/imido heterometathesis catalysts based on well-defined silica-supported early transition metal oxo and imido complexes. (C) 2021 Elsevier B.V. All rights reserved.

引用

页数：41

共 50 条

[41] Atomic friction studies on well-defined surfaces
Bennewitz, R
Gnecco, E
Gyalog, T
Meyer, E
TRIBOLOGY LETTERS, 2001, 10 (1-2) : 51 - 56
[42] Atomic friction studies on well-defined surfaces
R. Bennewitz
E. Gnecco
T. Gyalog
E. Meyer
Tribology Letters, 2001, 10 : 51 - 56
[43] A well-defined, silica-supported tungsten imido alkylidene olefin metathesis catalyst
Rhers, Bouchra
Salameh, Alain
Baudouin, Anne
Quadrelli, Elsje Alessandra
Taoufik, Mostafa
Coperet, Christophe
Lefebvre, Frederic
Basset, Jean-Marie
Solans-Monfort, Xavier
Eisenstein, Odile
Lukens, Wayne W.
Lopez, Lordes Pia H.
Sinha, Amritanshu
Schrock, Richard R.
ORGANOMETALLICS, 2006, 25 (15) : 3554 - 3557
[44] Mesostructured Hybrid Organic-Silica Materials: Ideal Supports for Well-Defined Heterogeneous Organometallic Catalysts
Conley, Matthew P.
Coperet, Christophe
Thieuleux, Chloe
ACS CATALYSIS, 2014, 4 (05): : 1458 - 1469
[45] Cyclopolymerization of 1,6-heptadiynes by well-defined molybdenum imido alkylidene initiators
Adamchuk, J
Schrock, RR
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U1061 - U1061
[46] Heterogeneous Catalysts with Well-Defined Active Metal Sites toward CO2 Electrocatalytic Reduction
Yang, Deren
Ni, Bing
Wang, Xun
ADVANCED ENERGY MATERIALS, 2020, 10 (25)
[47] Materials and composites from cellulose with well-defined molecular and supramolecular order
Klemm, Dieter O.
Kramer, Friederike
Kamitakahara, Hiroshi
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
[48] Preparation of well-defined, metathetically active oxo alkylidene complexes of tungsten
ODonoghue, MB
Schrock, RR
LaPointe, AM
Davis, WM
ORGANOMETALLICS, 1996, 15 (05) : 1334 - 1336
[49] Well-Defined Catalytic System for Integrating Homogeneous and Heterogeneous Catalysis
Wang, Hongli
Sun, Jiashu
He, Dongcheng
Zhao, Kang
Qian, Bo
Shi, Feng
ACS CATALYSIS, 2024, 14 (21): : 16025 - 16043
[50] Well-Defined Alkyne Metathesis Catalysts: Developments and Recent Applications
Ehrhorn, Henrike
Tamm, Matthias
CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (13) : 3190 - 3208

← 1 2 3 4 5 →