Oxo/imido heterometathesis: From molecular stoichiometric studies to well-defined heterogeneous catalysts

被引：9

作者：

Zhizhko, Pavel A. ^{[1
]}

Bushkov, Nikolai S. ^{[1
,2
]}

Pichugov, Andrey, V ^{[1
,3
]}

Zarubin, Dmitry N. ^{[1
]}

机构：

[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilov Str 28, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Vorobevy Gory 1, Moscow 119991, Russia

[3] D Mendeleev Univ Chem Technol Russia, Higher Chem Coll, Miusskaya Sq 9, Moscow 125047, Russia

来源：

COORDINATION CHEMISTRY REVIEWS | 2021年 / 448卷

基金：

俄罗斯科学基金会;

关键词：

Imido; Oxo; Metathesis; Heterometathesis; Cycloaddition; Surface Organometallic Chemistry; SURFACE ORGANOMETALLIC CHEMISTRY; TRANSITION-METAL-COMPLEXES; TITANIUM IMIDO COMPLEXES; SOLID-STATE NMR; OLEFIN-METATHESIS CATALYSTS; 2+2 CYCLOADDITION REACTIONS; CARBON-DIOXIDE ACTIVATION; HYDROGEN BOND ACTIVATION; NITROGEN-ATOM EXCHANGE; C-H ACTIVATION;

D O I：

10.1016/j.ccr.2021.214112

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxo/imido heterometathesis is a class of reactions that interconvert terminal transition metal oxo and imido complexes via [2 + 2] cycloaddition/cycloreversion with heteroolefins and heterocumulenes containing oxo and imino groups. In this review we summarize the literature examples of stoichiometric oxo/imido heterometathesis reactions of imido complexes with different oxo substrates and discuss the current progress in the development of catalytic oxo/imido heterometathesis. In particular, we show how application of Surface Organometallic Chemistry approach allows preparation of highly efficient oxo/imido heterometathesis catalysts based on well-defined silica-supported early transition metal oxo and imido complexes. (C) 2021 Elsevier B.V. All rights reserved.

引用

页数：41

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