Copper-catalyzed coupling of hydroxylamines with aryl iodides

被引：51

作者：

Jones, Kerri L. ^{[1
]}

Porzelle, Achim ^{[1
]}

Hall, Adrian ^{[2
]}

Woodrow, Michael D. ^{[3
]}

Tomkinson, Nicholas C. O. ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

[2] GlaxoSmithKline, Harlow CM19 5AW, Essex, England

[3] GlaxoSmithKline, Stevenage SG1 2NY, Herts, England

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/ol7029273

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient method for the copper-catalyzed N-arylation of hydroxylamines with aryl iodides is described. A variety of M and O-functionalized hydroxylamines were transformed in good to excellent yield with a broad range of aryl coupling partners. Methods for the selective deprotection of either the N- or O-substituents for further functionalization are also described.

引用

页码：797 / 800

页数：4

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