Synthesis of Platinum(II) Metallocycles Using Microwave-Assisted Heating

被引：23

作者：

Lopez-Vidal, Eva M. ^{[1
]}

Blanco, Victor ^{[1
]}

Garcia, Marcos D. ^{[1
]}

Peinador, Carlos ^{[1
]}

Quintela, Jose M. ^{[1
]}

机构：

[1] Univ A Coruna, Fac Ciencias, Dept Quim Fundamental, La Coruna 15008, Spain

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 02期

关键词：

ORGANIC-SYNTHESIS; MOLECULAR LOCK; COMPLEXES; LIGAND; CAVITY; CAGE; 2,2'-BIPYRIDINE; STRATEGIES; PD(II); GUESTS;

D O I：

10.1021/ol203191b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient microwave-assisted self-assembly of dinuclear platinum metallocycles is reported. The reactions proceed to afford the products with high purity and yields within 3-4 h. We have used this methodology to synthesize a new 14.75 angstrom x 14.75 angstrom molecular square. The solid-state structure showed a perfect alignment of the squares along the c axis.

引用

页码：580 / 583

页数：4

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