Synthesis of Platinum(II) Metallocycles Using Microwave-Assisted Heating

被引:23
|
作者
Lopez-Vidal, Eva M. [1 ]
Blanco, Victor [1 ]
Garcia, Marcos D. [1 ]
Peinador, Carlos [1 ]
Quintela, Jose M. [1 ]
机构
[1] Univ A Coruna, Fac Ciencias, Dept Quim Fundamental, La Coruna 15008, Spain
关键词
ORGANIC-SYNTHESIS; MOLECULAR LOCK; COMPLEXES; LIGAND; CAVITY; CAGE; 2,2'-BIPYRIDINE; STRATEGIES; PD(II); GUESTS;
D O I
10.1021/ol203191b
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An efficient microwave-assisted self-assembly of dinuclear platinum metallocycles is reported. The reactions proceed to afford the products with high purity and yields within 3-4 h. We have used this methodology to synthesize a new 14.75 angstrom x 14.75 angstrom molecular square. The solid-state structure showed a perfect alignment of the squares along the c axis.
引用
收藏
页码:580 / 583
页数:4
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