One-pot stereoselective synthesis of dimethyl(2-hydroxy-4,4-dimethylcyclohex-1-en-6-one-1-yl)-3-(diphenylphosphonato)butanedioate

被引：104
|
作者：
Yavari, I [1 ]
Ramazani, A [1 ]
机构：
[1] Tarbiat Modarres Univ, Dept Chem, Tehran, Iran
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1997年 / 130卷
关键词：
phosphonato ester; triphenyl phosphite; acetylenic ester; CH-acid; NMR spectroscopy; stereochemistry;
D O I：
10.1080/10426509708033699
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Protonation of the reactive intermediate produced in the reaction between triphenyl phosphite and dimethyl acetylenedicarboxylate by 5,5-dimethylcyclohexane-1,3-dione leads to vinyltriphenoxy-phosphonium cation, which undergoes an addition reaction with the enolate anion of the CH-acid to produce the title compound in high yield.
引用
收藏
页码：73 / 77
页数：5
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