One-pot stereoselective synthesis of dimethyl(2-hydroxy-4,4-dimethylcyclohex-1-en-6-one-1-yl)-3-(diphenylphosphonato)butanedioate

被引：104

作者：

Yavari, I ^{[1
]}

Ramazani, A ^{[1
]}

机构：

[1] Tarbiat Modarres Univ, Dept Chem, Tehran, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1997年 / 130卷

关键词：

phosphonato ester; triphenyl phosphite; acetylenic ester; CH-acid; NMR spectroscopy; stereochemistry;

D O I：

10.1080/10426509708033699

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Protonation of the reactive intermediate produced in the reaction between triphenyl phosphite and dimethyl acetylenedicarboxylate by 5,5-dimethylcyclohexane-1,3-dione leads to vinyltriphenoxy-phosphonium cation, which undergoes an addition reaction with the enolate anion of the CH-acid to produce the title compound in high yield.

引用

页码：73 / 77

页数：5

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