Acid-catalyzed isomerization of α-thevinone and α-dihydrothevinone into β-thevinone and β-dihydrothevinone

被引：0
|
作者：
Garadnay, S [1 ]
Marton, J [1 ]
Makleit, S [1 ]
机构：
[1] Univ Debrecen, Dept Organ Chem, H-4010 Debrecen, Hungary
来源：
ACH-MODELS IN CHEMISTRY | 2000年 / 137卷 / 5-6期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple, convenient, and most useful acid-catalyzed methodology was elaborated for the preparation of beta -thevinone (3a) and beta -dihydrothevinone (3b), which are starting materials of the so-called beta -Bentley-type compounds. The results also provide experimental evidences for the stability of the two pairs of diastereoisomeric ketones (2a-3a and 2b-3b).
引用
收藏
页码：789 / 792
页数：4
相关论文
共 50 条
  • [41] ACID-CATALYZED ISOMERIZATION OF CYCLOBUTYL KETONES - CONVENIENT SYNTHESIS OF SUBSTITUTED CYCLOPENTANONES
    LARCHEVEQUE, M
    MULOT, P
    CUVIGNY, T
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1975, 280 (05): : 309 - 311
  • [42] THE ACID-CATALYZED ISOMERIZATION OF CYCLOHEXYL PHENYL KETOXIME IN LIQUID SULFUR DIOXIDE
    TOKURA, N
    SHIINA, K
    TERASHIMA, T
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1962, 35 (12) : 1986 - 1989
  • [43] SOLVENT ISOTOPE EFFECT IN ACID-CATALYZED ISOMERIZATION OF CIS-STILBENES
    NOYCE, DS
    HARTTER, DR
    MILES, FB
    JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (11): : 4260 - &
  • [44] Scope and limitation of the acid-catalyzed isomerization of Aib-containing thiopeptides
    Breitenmoser, RA
    Heimgartner, H
    HELVETICA CHIMICA ACTA, 2001, 84 (04) : 786 - 796
  • [45] Altered Mechanisms for Acid-Catalyzed RNA Cleavage and Isomerization Reactions Models
    Xu, Yuqing
    Harris, Michael E.
    York, Darrin M.
    Wong, Kin-Yiu
    JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2023, 19 (04) : 1322 - 1332
  • [46] ACID-CATALYZED ISOMERIZATION OF THE [2+1]-CYCLODIMER OF AN IMINOPHOSPHANE TO THE DIAZADIPHOSPHETIDINE
    NIECKE, E
    GUDAT, D
    SYMALLA, E
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (09): : 834 - 835
  • [47] ACID-CATALYZED ISOMERIZATION AND CLEAVAGE OF DIOXIMES OF THE PHOTODIMERS OF GAMMA-PYRONES
    YATES, P
    HAND, ES
    TETRAHEDRON LETTERS, 1961, (19) : 669 - 675
  • [48] ACID-CATALYZED REACTIONS .7. EXAMPLE OF ABNORMAL BACKBONE ISOMERIZATION
    AMBLES, A
    JACQUESY, JC
    JACQUESY, R
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE PARTIE II-CHIMIE MOLECULAIRE ORGANIQUE ET BIOLOGIQUE, 1973, (9-10): : 2865 - 2866
  • [49] Acid-catalyzed isomerization and decomposition of ketone-2,4-dinitrophenylhydrazones
    Uchiyama, Shigehisa
    Kaneko, Toshiro
    Tokunaga, Hiroshi
    Ando, Masanori
    Otsubo, Yasufumi
    ANALYTICA CHIMICA ACTA, 2007, 605 (02) : 198 - 204
  • [50] ACID-CATALYZED ISOMERIZATION OF BICYCLO[6.1.0]NONANES FUNCTIONALISED AT POSITION 4
    GRAS, JL
    BERTRAND, M
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1972, (05): : 2024 - &
12345