1,1′-Bis(trimethylsilylseleno)ferrocene in cluster synthesis:: a redox active surface on a copper-selenide core

被引：35
|
作者：
Wallbank, AI [1 ]
Corrigan, JF [1 ]
机构：
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 04期
关键词：
D O I：
10.1039/b010023o
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
1,1'-Bis(trimethylsilylseleno)ferrocene 1 has been prepared from the reaction of [1,1'-Fe(eta (5)-C5H4SeLi)(2)(TMEDA)] and ClSiMe3 in good yield. The reactive silyl groups on 1 are used as a driving force for the synthesis of [Cu-8{Fe(eta (5)-C5H4Se)(2)}(4)(PPh2Et)(4)] 2, a cluster possessing four peripheral ferrocenyl moieties.
引用
收藏
页码：377 / 378
页数：2
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