1,1′-Bis(trimethylsilylseleno)ferrocene in cluster synthesis:: a redox active surface on a copper-selenide core

被引：35

作者：

Wallbank, AI ^{[1
]}

Corrigan, JF ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 04期

关键词：

D O I：

10.1039/b010023o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,1'-Bis(trimethylsilylseleno)ferrocene 1 has been prepared from the reaction of [1,1'-Fe(eta (5)-C5H4SeLi)(2)(TMEDA)] and ClSiMe3 in good yield. The reactive silyl groups on 1 are used as a driving force for the synthesis of [Cu-8{Fe(eta (5)-C5H4Se)(2)}(4)(PPh2Et)(4)] 2, a cluster possessing four peripheral ferrocenyl moieties.

引用

页码：377 / 378

页数：2

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