Catalytic performance and characterization of Ni-Fe catalysts for the steam reforming of tar from biomass pyrolysis to synthesis gas

被引：311
|
作者：
Wang, Lei [1 ]
Li, Dalin [1 ,2 ]
Koike, Mitsuru [3 ]
Koso, Shuichi [1 ]
Nakagawa, Yoshinao [1 ,2 ]
Xu, Ya [4 ]
Tomishige, Keiichi [1 ,2 ,3 ]
机构：
[1] Tohoku Univ, Sch Engn, Dept Appl Chem, Aoba Ku, Sendai, Miyagi 9808579, Japan
[2] CREST, Japan Sci & Technol Agcy, Aoba Ku, Sendai, Miyagi 9808579, Japan
[3] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058573, Japan
[4] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan
来源：
APPLIED CATALYSIS A-GENERAL | 2011年 / 392卷 / 1-2期
基金：
日本科学技术振兴机构;
关键词：
Biomass; Tar; Steam reforming; Ni; Fe; Alloy; Synthesis gas; SOLID-SOLUTION CATALYSTS; FLUIDIZED-BED GASIFICATION; PRESSURIZED CONDITIONS; PARTIAL OXIDATION; NOBLE-METALS; RH/CEO2/SIO2; CATALYSTS; CARBON DEPOSITION; NICKEL-CATALYSTS; LOW-TEMPERATURE; METHANE-STEAM;
D O I：
10.1016/j.apcata.2010.11.013
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Catalytic performance of Ni-Fe/Al2O3 catalysts with the optimum composition was much higher than corresponding monometallic Ni and Fe catalysts in the steam reforming of tar from the pyrolysis of cedar wood. According to the catalyst characterization, the Ni-Fe alloys were formed and the Fe atoms on the alloys tend to be enriched on the surface, and it was suggested that the structure was maintained mainly during the reaction. The surface Fe atoms supply oxygen species, enhancing the reaction of tar and suppressing the coke formation. Excess Fe addition decreased the catalytic activity by decreasing the surface Ni atoms. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：248 / 255
页数：8
相关论文
共 50 条
  • [41] Catalytic characteristics of innovative Ni/slag catalysts for syngas production and tar removal from biomass pyrolysis
    Liu, Yang
    Yu, Haimiao
    Liu, Jiecheng
    Chen, Dezhen
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (23) : 11848 - 11860
  • [42] Steam reforming of tar derived from the steam pyrolysis of biomass over metal catalyst supported on zeolite
    Kaewpanha, Malinee
    Guan, Guoqing
    Hao, Xiaogang
    Wang, Zhongde
    Kasai, Yutaka
    Kakuta, Seiji
    Kusakabe, Kastuki
    Abudula, Abuliti
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2013, 44 (06) : 1022 - 1026
  • [43] Investigation of Ni-Fe-Cu-Layered Double Hydroxide Catalysts in Steam Reforming of Toluene as a Model Compound of Biomass Tar
    Diez, David
    Uruena, Ana
    Antolin, Gregorio
    PROCESSES, 2021, 9 (01) : 1 - 21
  • [44] Development of Ni-Fe bimetallic based catalysts for biomass tar cracking/reforming: Effects of catalyst support and co-fed reactants on tar conversion characteristics
    Laosiripojana, N.
    Sutthisripok, W.
    Charojrochkul, S.
    Assabumrungrat, S.
    FUEL PROCESSING TECHNOLOGY, 2014, 127 : 26 - 32
  • [45] Steam reforming of bagasse to hydrogen and synthesis gas using ruthenium promoted Ni-Fe/γ-Al2O3nano-catalysts
    Jafarian, Sajedeh
    Tavasoli, Ahmad
    Karimi, Ali
    Norouzi, Omid
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (08) : 5505 - 5512
  • [46] Hydrochar supported bimetallic Ni-Fe nanocatalysts with tailored composition, size and shape for improved biomass steam reforming performance
    Gai, Chao
    Zhang, Fang
    Yang, Tianxue
    Liu, Zhengang
    Jiao, Wentao
    Peng, Nana
    Liu, Tingting
    Lang, Qianqian
    Xia, Yu
    GREEN CHEMISTRY, 2018, 20 (12) : 2788 - 2800
  • [47] Catalytic reforming of biomass pyrolysis gas over Ni catalysts: Alumina, spent fluid catalytic cracking catalyst and char as supports
    Low, Ching Wei
    Veksha, Andrei
    Aryal, Rupendra
    Chan, Wei Ping
    Lisak, Grzegorz
    APPLIED CATALYSIS A-GENERAL, 2025, 691
  • [48] Ni-Fe catalysts derived from hydrotalcite-like precursors for hydrogen production by ethanol steam reforming
    Abello, Sonia
    Bolshak, Evgeniy
    Montane, Daniel
    APPLIED CATALYSIS A-GENERAL, 2013, 450 : 261 - 274
  • [49] Preparation, modification and development of Ni-based catalysts for catalytic reforming of tar produced from biomass gasification
    Zhang, Zhikun
    Liu, Lina
    Shen, Boxiong
    Wu, Chunfei
    RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2018, 94 : 1086 - 1109
  • [50] Production of synthesis gas by partial oxidation and steam reforming of biomass pyrolysis oils
    Rennard, David
    French, Rick
    Czernik, Stefan
    Josephson, Tyler
    Schmidt, Lanny
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (09) : 4048 - 4059
12345