Catalytic performance and characterization of Ni-Fe catalysts for the steam reforming of tar from biomass pyrolysis to synthesis gas

被引：311

作者：

Wang, Lei ^{[1
]}

Li, Dalin ^{[1
,2
]}

Koike, Mitsuru ^{[3
]}

Koso, Shuichi ^{[1
]}

Nakagawa, Yoshinao ^{[1
,2
]}

Xu, Ya ^{[4
]}

Tomishige, Keiichi ^{[1
,2
,3
]}

机构：

[1] Tohoku Univ, Sch Engn, Dept Appl Chem, Aoba Ku, Sendai, Miyagi 9808579, Japan

[2] CREST, Japan Sci & Technol Agcy, Aoba Ku, Sendai, Miyagi 9808579, Japan

[3] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058573, Japan

[4] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan

来源：

APPLIED CATALYSIS A-GENERAL | 2011年 / 392卷 / 1-2期

基金：

日本科学技术振兴机构;

关键词：

Biomass; Tar; Steam reforming; Ni; Fe; Alloy; Synthesis gas; SOLID-SOLUTION CATALYSTS; FLUIDIZED-BED GASIFICATION; PRESSURIZED CONDITIONS; PARTIAL OXIDATION; NOBLE-METALS; RH/CEO2/SIO2; CATALYSTS; CARBON DEPOSITION; NICKEL-CATALYSTS; LOW-TEMPERATURE; METHANE-STEAM;

D O I：

10.1016/j.apcata.2010.11.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic performance of Ni-Fe/Al2O3 catalysts with the optimum composition was much higher than corresponding monometallic Ni and Fe catalysts in the steam reforming of tar from the pyrolysis of cedar wood. According to the catalyst characterization, the Ni-Fe alloys were formed and the Fe atoms on the alloys tend to be enriched on the surface, and it was suggested that the structure was maintained mainly during the reaction. The surface Fe atoms supply oxygen species, enhancing the reaction of tar and suppressing the coke formation. Excess Fe addition decreased the catalytic activity by decreasing the surface Ni atoms. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：248 / 255

页数：8

共 50 条

[21] Waste ashes as catalysts for the pyrolysis–catalytic steam reforming of biomass for hydrogen-rich gas production
Amal S. Al-Rahbi
Paul T. Williams
Journal of Material Cycles and Waste Management, 2019, 21 : 1224 - 1231
[22] Steam Reforming of Tar Derived from Biomass Pyrolysis over Ni-MnOx/SBA-15 Catalysts at Low Temperature
Hlaing, Nwaynay
Kawahara, Kazuya
Nakagoe, Osamu
Zheng, Guobin
Sano, Hideaki
Tanabe, Shuji
CHEMISTRY LETTERS, 2018, 47 (09) : 1131 - 1134
[23] Catalytic reforming of biomass primary tar from pyrolysis over waste steel slag based catalysts
Guo, Feiqiang
Zhao, Xingmin
Peng, Kuangye
Liang, Shuang
Jia, Xiaopeng
Qian, Lin
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (31) : 16224 - 16233
[24] The influence of preparation method of char supported metallic Ni catalysts on the catalytic performance for reforming of biomass tar
Xu, Dan
Xiong, Yuanquan
Zhang, Shuping
Su, Yinhai
INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2019, 43 (13) : 6922 - 6933
[25] Characterization and evaluation of Ni/SiO2 catalysts for hydrogen production and tar reduction from catalytic steam pyrolysis-reforming of refuse derived fuel
Blanco, Paula H.
Wu, Chunfei
Onwudili, Jude A.
Williams, Paul T.
APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 134 : 238 - 250
[26] Ni/Al coprecipitated catalysts modified with magnesium and copper for the catalytic steam reforming of model compounds from biomass pyrolysis liquids
Bimbela, F.
Chen, D.
Ruiz, J.
Garcia, L.
Arauzo, J.
APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 119 : 1 - 12
[27] Hydrogen from biomass by catalytic steam reforming of biomass pyrolysis vapors.
Evans, RJ
Chornet, E
Czernik, S
Feik, C
French, R
Phillips, S
Yeboah, YD
Day, D
Ellis, S
McGee, D
Realff, MJ
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U536 - U536
[28] Waste ashes as catalysts for the pyrolysis-catalytic steam reforming of biomass for hydrogen-rich gas production
Al-Rahbi, Amal S.
Williams, Paul T.
JOURNAL OF MATERIAL CYCLES AND WASTE MANAGEMENT, 2019, 21 (05) : 1224 - 1231
[29] Metal catalysts for steam reforming of tar derived from the gasification of lignocellulosic biomass
Li, Dalin
Tamura, Masazumi
Nakagawa, Yoshinao
Tomishige, Keiichi
BIORESOURCE TECHNOLOGY, 2015, 178 : 53 - 64
[30] Synthesis of modified char-supported Ni-Fe catalyst with hierarchical structure for catalytic cracking of biomass tar
Lin, Qunqing
Zhang, Shuping
Wang, Jiaxing
Yin, Haoxin
RENEWABLE ENERGY, 2021, 174 : 188 - 198

← 1 2 3 4 5 →