Development of a Mild Procedure for the Addition of Bisulfite to Electrophilic Olefins

被引：40
|
作者：
Fini, Francesco [1 ]
Nagabelli, Murali [1 ]
Adamo, Mauro F. A. [1 ]
机构：
[1] Royal Coll Surgeons Ireland, Ctr Synth & Chem Biol, Dept Pharmaceut & Med Chem, Dublin 2, Ireland
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2010年 / 352卷 / 18期
关键词：
alkenes; amine catalysis; sulfonic acids; thia-Mchael addition; triethylamine; AMINO-CYCLOHEXYL SULFONATES; ASYMMETRIC-SYNTHESIS; ACIDS; RESOLUTION; ION;
D O I：
10.1002/adsc.201000543
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The sulfonylation of activated alkenes is an important yet unexplored reaction due to the harshness of conditions required. We have identified a procedure which allowed the reaction of alkenes with equimolar amounts of bisulfite at room temperature.
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页码：3163 / 3168
页数：6
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