Development of a Mild Procedure for the Addition of Bisulfite to Electrophilic Olefins

被引：40

作者：

Fini, Francesco ^{[1
]}

Nagabelli, Murali ^{[1
]}

Adamo, Mauro F. A. ^{[1
]}

机构：

[1] Royal Coll Surgeons Ireland, Ctr Synth & Chem Biol, Dept Pharmaceut & Med Chem, Dublin 2, Ireland

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2010年 / 352卷 / 18期

关键词：

alkenes; amine catalysis; sulfonic acids; thia-Mchael addition; triethylamine; AMINO-CYCLOHEXYL SULFONATES; ASYMMETRIC-SYNTHESIS; ACIDS; RESOLUTION; ION;

D O I：

10.1002/adsc.201000543

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The sulfonylation of activated alkenes is an important yet unexplored reaction due to the harshness of conditions required. We have identified a procedure which allowed the reaction of alkenes with equimolar amounts of bisulfite at room temperature.

引用

页码：3163 / 3168

页数：6

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