Recent applications of chiral phosphoric acids in palladium catalysis

被引：36
|
作者：
Tran, Van T. [1 ]
Nimmagadda, Sri Krishna [1 ]
Liu, Mingyu [1 ]
Engle, Keary M. [1 ]
机构：
[1] Scripps Res Inst, Dept Chem, 10550 N Torrey Pines Rd,BCC 169, La Jolla, CA 92037 USA
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2020年 / 18卷 / 04期
基金：
美国国家卫生研究院;
关键词：
C-H ARYLATION; PD(0)-CATALYZED ENANTIOSELECTIVE 1,1-DIARYLATION; ANION PHASE-TRANSFER; BRONSTED ACID; COOPERATIVE CATALYSIS; ALLYLIC ALCOHOLS; CARBONYL ALLYLATION; ALPHA-ALLYLATION; METAL CATALYSIS; HOMOALLYLIC ALCOHOLS;
D O I：
10.1039/c9ob02205h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Through the combined action of palladium catalysts and chiral phosphoric acids (CPAs) a variety of catalytic asymmetric reactions have been realized during the past decade, including allylation, alkene functionalization, and C-H activation. This review surveys key examples across these various reaction types and examines the different mechanisms by which CPAs can affect stereoinduction in these reaction systems.
引用
收藏
页码：618 / 637
页数：20
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