Recent applications of chiral phosphoric acids in palladium catalysis

被引：36

作者：

Tran, Van T. ^{[1
]}

Nimmagadda, Sri Krishna ^{[1
]}

Liu, Mingyu ^{[1
]}

Engle, Keary M. ^{[1
]}

机构：

[1] Scripps Res Inst, Dept Chem, 10550 N Torrey Pines Rd,BCC 169, La Jolla, CA 92037 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2020年 / 18卷 / 04期

基金：

美国国家卫生研究院;

关键词：

C-H ARYLATION; PD(0)-CATALYZED ENANTIOSELECTIVE 1,1-DIARYLATION; ANION PHASE-TRANSFER; BRONSTED ACID; COOPERATIVE CATALYSIS; ALLYLIC ALCOHOLS; CARBONYL ALLYLATION; ALPHA-ALLYLATION; METAL CATALYSIS; HOMOALLYLIC ALCOHOLS;

D O I：

10.1039/c9ob02205h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Through the combined action of palladium catalysts and chiral phosphoric acids (CPAs) a variety of catalytic asymmetric reactions have been realized during the past decade, including allylation, alkene functionalization, and C-H activation. This review surveys key examples across these various reaction types and examines the different mechanisms by which CPAs can affect stereoinduction in these reaction systems.

引用

页码：618 / 637

页数：20

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