Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water

被引：4

作者：

Liu, Shi-juan ^{[1
,2
]}

Zhang, Miao ^{[2
]}

Lu, Rong ^{[2
]}

Li, Xiu-ying ^{[1
,2
]}

Che, Guang-bo ^{[1
]}

机构：

[1] Jilin Normal Univ, Minist Educ, Key Lab Preparat & Applicat Environm Friendly Mat, Changchun 130103, Jilin, Peoples R China

[2] Jilin Normal Univ, Coll Chem, Siping 136000, Peoples R China

来源：

MOLECULES | 2018年 / 23卷 / 08期

基金：

中国国家自然科学基金;

关键词：

sodium copper chlorophyllin; oxidation; alcohols; chemoselectivity; water; AEROBIC OXIDATION; PROPARGYLIC ALCOHOLS; ALDEHYDES; EFFICIENT; ABSORPTION; PORPHYRINS; PRODUCTS; KETONES;

D O I：

10.3390/molecules23081883

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

We report the highly efficient and chemoselective oxidation of benzylic alcohols catalyzed by sodium copper chlorophyllin in water, producing corresponding arylcarbonyl compounds. Importantly, the catalytic system exhibits a wide substrate scope and high functional group tolerance. Moreover, secondary alcohols and even diarylmethanes were smoothly oxidized to the desired aryl ketones with excellent yields.

引用

页数：7

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