Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water

被引：4
|
作者：
Liu, Shi-juan [1 ,2 ]
Zhang, Miao [2 ]
Lu, Rong [2 ]
Li, Xiu-ying [1 ,2 ]
Che, Guang-bo [1 ]
机构：
[1] Jilin Normal Univ, Minist Educ, Key Lab Preparat & Applicat Environm Friendly Mat, Changchun 130103, Jilin, Peoples R China
[2] Jilin Normal Univ, Coll Chem, Siping 136000, Peoples R China
来源：
MOLECULES | 2018年 / 23卷 / 08期
基金：
中国国家自然科学基金;
关键词：
sodium copper chlorophyllin; oxidation; alcohols; chemoselectivity; water; AEROBIC OXIDATION; PROPARGYLIC ALCOHOLS; ALDEHYDES; EFFICIENT; ABSORPTION; PORPHYRINS; PRODUCTS; KETONES;
D O I：
10.3390/molecules23081883
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
We report the highly efficient and chemoselective oxidation of benzylic alcohols catalyzed by sodium copper chlorophyllin in water, producing corresponding arylcarbonyl compounds. Importantly, the catalytic system exhibits a wide substrate scope and high functional group tolerance. Moreover, secondary alcohols and even diarylmethanes were smoothly oxidized to the desired aryl ketones with excellent yields.
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页数：7
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