Electroconductive films based on amino-substituted tetraphenylporphyrins and their metal copper complexes

被引：25

作者：

Tesakova, Mariya V. ^{[1
]}

Semeikin, Aleksandr S. ^{[2
]}

Parfenyuk, Vladimir I. ^{[1
]}

机构：

[1] RAS, GA Krestov Inst Solut Chem, Akad Skaya St 1, Ivanovo 153045, Russia

[2] Ivanovo State Univ Chem & Technol, Sheremetevsky Ave 7, Ivanovo 153000, Russia

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2016年 / 20卷 / 07期

关键词：

porphyrins; metalloporphyrins; electropolymerization; polyporphyrin films; cyclic voltammetry; ELECTRONIC-STRUCTURE; COATED ELECTRODES; NITRIC-OXIDE; PORPHYRIN; OXIDATION; ELECTROPOLYMERIZATION; POLYMERIZATION; ANILINE; SENSOR; WATER;

D O I：

10.1142/S1088424616500930

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Amino-substituted tetraphenylporphyrins (5,10,15,20-tetrakis(4'-aminophenyl) porphyrin, 5-(4'-aminophenyl)-10,15,20-triphenylporphyrin) and their copper complexes in dichloromethane and ethanol were electropolymerized by the cyclic voltammetry method and their electrochemical properties were studied. The polyporphyrin films obtained by electro-oxidation transmit electricity and possess semiconductor properties of different types. The poly-5,10,15,20-tetrakis(4'-aminophenyl) porphyrin films obtained from different solvents are similar to each other in chemical composition but different in morphology. The polyporphyrin film surface morphology was studied by AFM microscopy.

引用

页码：793 / 803

页数：11

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