Electroconductive films based on amino-substituted tetraphenylporphyrins and their metal copper complexes

被引：25
|
作者：
Tesakova, Mariya V. [1 ]
Semeikin, Aleksandr S. [2 ]
Parfenyuk, Vladimir I. [1 ]
机构：
[1] RAS, GA Krestov Inst Solut Chem, Akad Skaya St 1, Ivanovo 153045, Russia
[2] Ivanovo State Univ Chem & Technol, Sheremetevsky Ave 7, Ivanovo 153000, Russia
来源：
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2016年 / 20卷 / 07期
关键词：
porphyrins; metalloporphyrins; electropolymerization; polyporphyrin films; cyclic voltammetry; ELECTRONIC-STRUCTURE; COATED ELECTRODES; NITRIC-OXIDE; PORPHYRIN; OXIDATION; ELECTROPOLYMERIZATION; POLYMERIZATION; ANILINE; SENSOR; WATER;
D O I：
10.1142/S1088424616500930
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Amino-substituted tetraphenylporphyrins (5,10,15,20-tetrakis(4'-aminophenyl) porphyrin, 5-(4'-aminophenyl)-10,15,20-triphenylporphyrin) and their copper complexes in dichloromethane and ethanol were electropolymerized by the cyclic voltammetry method and their electrochemical properties were studied. The polyporphyrin films obtained by electro-oxidation transmit electricity and possess semiconductor properties of different types. The poly-5,10,15,20-tetrakis(4'-aminophenyl) porphyrin films obtained from different solvents are similar to each other in chemical composition but different in morphology. The polyporphyrin film surface morphology was studied by AFM microscopy.
引用
收藏
页码：793 / 803
页数：11
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