Biodegradable PLA-based composites modified by POSS particles

被引:14
|
作者
Chen, Yi [1 ,2 ]
Liu, Shuichang [1 ,2 ]
Zhou, Yueyun [1 ,3 ]
Zeng, Guangsheng [1 ,2 ]
Liu, Wenyong [2 ]
机构
[1] Hunan Univ Technol, Hunan Prov Engn Lab Key Tech Nonmetall Packaging, Zhuzhou, Peoples R China
[2] Hunan Univ Technol, Hunan Prov Key Lab Biomass Fiber Funct Mat, Zhuzhou, Peoples R China
[3] Hunan Univ Technol, Coll Urban & Environm Sci, Hunan Prov Key Lab Comprehens Utilizat Agr & Anim, Zhuzhou, Peoples R China
来源
关键词
PLA; composites; POSS; reactive extrusion; POLYLACTIC ACID; POLY(LACTIC ACID); ALIPHATIC POLYCARBONATES; MECHANICAL-PROPERTIES; TOUGHNESS;
D O I
10.1080/25740881.2020.1719139
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The poly(lactic acid)(PLA)/aliphatic poly(carbonate)(PPC)/polyethylene glycol-polyhedral oligomeric silsesquioxane (PEG-POSS) composites were prepared by reactive melting extrusion. The effect of various components on the mechanical, thermal, rheological, and hydrophilic properties of composites was systematically studied by means of various characterization methods. The results showed that, with the increase of PPC content, the toughness of composites improves significantly, while the strength decreases. Reactive extrusion and adding PEG-POSS could enhance the compatibility and adjust the crystallization of composites effectively. When the proportion of PPC and PEG-POSS in composites is 20-40wt% and 4wt%, respectively, the composites own the best comprehensive performance.
引用
收藏
页码:998 / 1009
页数:12
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