Biodegradable PLA-based composites modified by POSS particles

被引:14
|
作者
Chen, Yi [1 ,2 ]
Liu, Shuichang [1 ,2 ]
Zhou, Yueyun [1 ,3 ]
Zeng, Guangsheng [1 ,2 ]
Liu, Wenyong [2 ]
机构
[1] Hunan Univ Technol, Hunan Prov Engn Lab Key Tech Nonmetall Packaging, Zhuzhou, Peoples R China
[2] Hunan Univ Technol, Hunan Prov Key Lab Biomass Fiber Funct Mat, Zhuzhou, Peoples R China
[3] Hunan Univ Technol, Coll Urban & Environm Sci, Hunan Prov Key Lab Comprehens Utilizat Agr & Anim, Zhuzhou, Peoples R China
来源
关键词
PLA; composites; POSS; reactive extrusion; POLYLACTIC ACID; POLY(LACTIC ACID); ALIPHATIC POLYCARBONATES; MECHANICAL-PROPERTIES; TOUGHNESS;
D O I
10.1080/25740881.2020.1719139
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The poly(lactic acid)(PLA)/aliphatic poly(carbonate)(PPC)/polyethylene glycol-polyhedral oligomeric silsesquioxane (PEG-POSS) composites were prepared by reactive melting extrusion. The effect of various components on the mechanical, thermal, rheological, and hydrophilic properties of composites was systematically studied by means of various characterization methods. The results showed that, with the increase of PPC content, the toughness of composites improves significantly, while the strength decreases. Reactive extrusion and adding PEG-POSS could enhance the compatibility and adjust the crystallization of composites effectively. When the proportion of PPC and PEG-POSS in composites is 20-40wt% and 4wt%, respectively, the composites own the best comprehensive performance.
引用
收藏
页码:998 / 1009
页数:12
相关论文
共 50 条
  • [21] Enhanced Extrusion Processability of PLA Blends through Rheology Control Using Biodegradable PLA-based Graft Polymers
    Choi, Kihong
    Gil, Jihoon
    Ju, Jinhyeok
    Li, Zhibo
    Jung, Hyun Wook
    Bang, Joona
    ACS APPLIED POLYMER MATERIALS, 2024, 7 (01): : 54 - 62
  • [22] Nanoscale piezoelectric effect of biodegradable PLA-based composite fibers by piezoresponse force microscopy
    Zheng, Tian
    Yue, Zhilian
    Wallace, Gordon G.
    Du, Yi
    Higgins, Michael J.
    NANOTECHNOLOGY, 2020, 31 (37)
  • [23] PLA-based ceramic composites for 3D printing of anthropomorphic simulators
    Eduardo Thomazi
    Celso Roman
    Thiago Oliveira Gamba
    Cláudio Antônio Perottoni
    Janete Eunice Zorzi
    The International Journal of Advanced Manufacturing Technology, 2023, 128 : 5289 - 5300
  • [24] PLA-based ceramic composites for 3D printing of anthropomorphic simulators
    Thomazi, Eduardo
    Roman, Celso
    Gamba, Thiago Oliveira
    Perottoni, Claudio Antonio
    Zorzi, Janete Eunice
    INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY, 2023, 128 (11-12): : 5289 - 5300
  • [25] Physico-chemical Characterization of PLA-based Composites Holding Carbon Nanofillers
    Batakliev, Todor
    Georgiev, Vladimir
    Kalupgian, Cristiane
    Munoz, Pablo A. R.
    Ribeiro, Helio
    Fechine, Guilhermino J. M.
    Andrade, Ricardo J. E.
    Ivanov, Evgeni
    Kotsilkova, Rumiana
    APPLIED COMPOSITE MATERIALS, 2021, 28 (04) : 1175 - 1192
  • [26] Effect of Modification of Flax Fibers with Silanes and Polysiloxanes on the Properties of PLA-Based Composites
    Gieparda, Weronika
    Rojewski, Szymon
    Przybylak, Marcin
    Doczekalska, Beata
    JOURNAL OF NATURAL FIBERS, 2023, 20 (02)
  • [27] Synthesis of PLA-based thermoplastic elastomer and study on preparation and properties of PLA-based shape memory polymers
    Ji, Fan
    Li, Jianbo
    Weng, Yunxuan
    Ren, Jie
    MATERIALS RESEARCH EXPRESS, 2020, 7 (01)
  • [28] Preparation of PLA-based SMS nonwoven composites and its applications in protective apparel
    Zhang, Yongmeng
    Ma, Wenhua
    Lin, Minggang
    Qi, Huan
    Zhang, Chuyang
    JOURNAL OF THE TEXTILE INSTITUTE, 2024, 115 (07) : 1021 - 1029
  • [29] Tensile, flexural and fracture properties of MEX-printed PLA-based composites
    Stoia, Dan Ioan
    Linul, Emanoil
    THEORETICAL AND APPLIED FRACTURE MECHANICS, 2024, 132
  • [30] Physico-chemical Characterization of PLA-based Composites Holding Carbon Nanofillers
    Todor Batakliev
    Vladimir Georgiev
    Cristiane Kalupgian
    Pablo A. R. Muñoz
    Hélio Ribeiro
    Guilhermino J. M. Fechine
    Ricardo J. E. Andrade
    Evgeni Ivanov
    Rumiana Kotsilkova
    Applied Composite Materials, 2021, 28 : 1175 - 1192