A supramolecular catalyst for regioselective hydroformylation of unsaturated carboxylic acids

被引：144

作者：

Smejkal, Tomas ^{[1
]}

Breit, Bernhard ^{[1
]}

机构：

[1] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 02期

关键词：

enzyme mimics; guanidine; homogeneous catalysis; hydroformylation; molecular recognition;

D O I：

10.1002/anie.200703192

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The quest to capture the catalytic power of enzymes is one of the great challenges of modern chemistry. A novel system inspired by the principles of enzymatic catalysis combines recognition of the substrate and transition-metal catalysis (see scheme; Do = donor, FG = functional group) and mimics enzyme properties - high efficiency, substrate selectivity, and reaction-site selectivity. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：311 / 315

页数：5

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