A supramolecular catalyst for regioselective hydroformylation of unsaturated carboxylic acids

被引：144
|
作者：
Smejkal, Tomas [1 ]
Breit, Bernhard [1 ]
机构：
[1] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 02期
关键词：
enzyme mimics; guanidine; homogeneous catalysis; hydroformylation; molecular recognition;
D O I：
10.1002/anie.200703192
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) The quest to capture the catalytic power of enzymes is one of the great challenges of modern chemistry. A novel system inspired by the principles of enzymatic catalysis combines recognition of the substrate and transition-metal catalysis (see scheme; Do = donor, FG = functional group) and mimics enzyme properties - high efficiency, substrate selectivity, and reaction-site selectivity. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：311 / 315
页数：5
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