Palladium(II)-catalyzed oxidation of alcohols with air as reoxidant

被引:0
|
作者
Hallman, K [1 ]
Moberg, C [1 ]
机构
[1] Royal Inst Technol, Dept Chem, SE-10044 Stockholm, Sweden
关键词
air; catalysts; homogeneous catalysis; metallacycles; oxidation; palladium;
D O I
10.1002/1615-4169(20010330)343:3<260::AID-ADSC260>3.3.CO;2-#
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Oxidation of primary and secondary aliphatic and secondary benzylic alcohols into their corresponding aldehydes and ketones was achieved in good yields with palladium catalysts using air as the reoxidant of palladium. The use of palladacycle 1 resulted in higher yields and a faster reaction than the use of Pd(OAc)(2) as the palladium source.
引用
收藏
页码:260 / 263
页数:4
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