Palladium(II)-catalyzed oxidation of alcohols with air as reoxidant

被引：0
|
作者：
Hallman, K [1 ]
Moberg, C [1 ]
机构：
[1] Royal Inst Technol, Dept Chem, SE-10044 Stockholm, Sweden
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2001年 / 343卷 / 03期
关键词：
air; catalysts; homogeneous catalysis; metallacycles; oxidation; palladium;
D O I：
10.1002/1615-4169(20010330)343:3<260::AID-ADSC260>3.3.CO;2-#
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Oxidation of primary and secondary aliphatic and secondary benzylic alcohols into their corresponding aldehydes and ketones was achieved in good yields with palladium catalysts using air as the reoxidant of palladium. The use of palladacycle 1 resulted in higher yields and a faster reaction than the use of Pd(OAc)(2) as the palladium source.
引用
收藏
页码：260 / 263
页数：4
相关论文
共 50 条
  • [11] The renaissance of palladium(II)-catalyzed oxidation chemistry
    Sigman, MS
    Schultz, MJ
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2004, 2 (18) : 2551 - 2554
  • [12] Iodine as a chemoselective reoxidant of TEMPO: Application to the oxidation of alcohols to aldehydes and ketones
    Miller, RA
    Hoerrner, RS
    ORGANIC LETTERS, 2003, 5 (03) : 285 - 287
  • [13] Iron(II)-Catalyzed Biomimetic Aerobic Oxidation of Alcohols
    Gudmundsson, Arnar
    Schlipkoeter, Kim Elisabeth
    Backvall, Jan-E.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (13) : 5403 - 5406
  • [14] Cu(II) bromide catalyzed oxidation of aldehydes and alcohols
    Das, Rima
    Chakraborty, Debashis
    APPLIED ORGANOMETALLIC CHEMISTRY, 2011, 25 (06) : 437 - 442
  • [15] Palladium-neocuproine catalyzed aerobic oxidation of alcohols in aqueous solvents
    Arends, IWCE
    ten Brink, GJ
    Sheldon, RA
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 251 (1-2) : 246 - 254
  • [16] Palladium-catalyzed oxidation of primary and secondary allylic and benzylic alcohols
    Peterson, KP
    Larock, RC
    JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (10): : 3185 - 3189
  • [17] Recent advances in the homogeneous palladium-catalyzed aerobic oxidation of alcohols
    Karimi, B.
    Zamani, A.
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2008, 5 (Suppl 1) : S1 - S20
  • [18] Palladium-catalyzed oxidation of octyl alcohols in "supercritical" carbon dioxide
    Jenzer, G
    Schneider, MS
    Wandeler, R
    Mallat, T
    Baiker, A
    JOURNAL OF CATALYSIS, 2001, 199 (01) : 141 - 148
  • [19] Productive utilization of chlorobenzene: Palladium-catalyzed selective oxidation of alcohols
    Guram, AS
    Bei, XH
    Turner, HW
    ORGANIC LETTERS, 2003, 5 (14) : 2485 - 2487
  • [20] Recent advances in the homogeneous palladium-catalyzed aerobic oxidation of alcohols
    B. Karimi
    A. Zamani
    Journal of the Iranian Chemical Society, 2008, 5 : S1 - S20
12345