Electrochemical micromachining of titanium through a patterned oxide film (oxyresist) has been achieved in a sulfuric acidmethanol-based electropolishing electrolyte. The patterned oxide film was formed in an aqueous 0.5 M sulfuric acid solution by selective anodic oxidation of titanium through a photoresist mask. Electrochemical dissolution through the patterned oxide film yielded well-defined grooves comparable to those obtained by etching directly through a photoresist mask. The described process eliminates the need for photoresists to be chemically stable in aggressive electropolishing electrolytes. It increases significantly the flexibility of implementation of electrochemical micromachining of valve metals. (C) 1999 The Electrochemical Society. S1099-0062(98)11-024-6 All rights reserved.
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Tokyo Inst Technol, Mat & Struct Lab, Ctr Mat Design, Midori Ku, Yokohama, Kanagawa 2268503, JapanTokyo Inst Technol, Mat & Struct Lab, Ctr Mat Design, Midori Ku, Yokohama, Kanagawa 2268503, Japan
Ibrahim, MAM
Pongkao, D
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Tokyo Inst Technol, Mat & Struct Lab, Ctr Mat Design, Midori Ku, Yokohama, Kanagawa 2268503, JapanTokyo Inst Technol, Mat & Struct Lab, Ctr Mat Design, Midori Ku, Yokohama, Kanagawa 2268503, Japan
机构:
University of Western Ontario, Department of Chemistry, Western University, London, ON N6A 5B7, CanadaUniversity of Western Ontario, Department of Chemistry, Western University, London, ON N6A 5B7, Canada
Qin, Z.
Zeng, Y.
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University of Western Ontario, Department of Chemistry, Western University, London, ON N6A 5B7, Canada
Kinectrics Inc., Toronto, ON M8Z 6C4, CanadaUniversity of Western Ontario, Department of Chemistry, Western University, London, ON N6A 5B7, Canada
Zeng, Y.
Shoesmith, D.W.
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University of Western Ontario, Department of Chemistry, Western University, London, ON N6A 5B7, CanadaUniversity of Western Ontario, Department of Chemistry, Western University, London, ON N6A 5B7, Canada