Phthalocyanines and related compounds: XLVI. [4+2]-cycloaddition of tetraazaporphine to dienes of the cyclopentadiene series

被引：6
|
作者：
Dudkin, S. V. [1 ]
Makarova, E. A. [1 ]
Luk'yanets, E. A. [1 ]
机构：
[1] Sci Res Inst Organ Half Prod & Dyes, Moscow 123995, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2008年 / 78卷 / 07期
基金：
俄罗斯基础研究基金会;
关键词：
Diene; General Chemistry; Phthalocyanine; Electronic Absorption Spectrum; Cyclopentadiene;
D O I：
10.1134/S1070363208070281
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The [4+2]-cycloaddition reaction of unsubstituted tetraazaporphine as the dienophile with a series of dienes of the cyclopentadiene series gave novel norbornene-condensed tetraazachlorins, tetraazabacteriochlorins, and tetraazaisobacteriochlorins. It was shown that, depending on the type of the diene, the reagent ratio, reaction time, and temperature mono-or bis-adducts are formed. The compounds obtained were characterized by the elemental analyses, electronic absorption spectra, H-1 NMR spectra, and mass spectra.
引用
收藏
页码：1441 / 1446
页数：6
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