Asymmetrical [4+2]-Cycloaddition of (-)-Menthyl Acrylate and (-)-Menthyl Methacrylate to Cyclopentadiene in the Presence of BBr3

被引：0

作者：

E.G. Mamedov

机构：

[1] Institute of Petrochemical Processes,Azerbaidzhan Academy of Sciences

来源：

Russian Journal of Organic Chemistry | 2001年 / 37卷

关键词：

Chromatography; Organic Chemistry; Boiling; Methacrylate; Acrylate;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

An asymmetrical synthesis of bicyclo[2.2.1]hept-2-enes is described performed by [4+2]-cyclo-addition of (-)-menthyl acrylate, (-)-menthyl methacrylate to cyclopentadiene in the presence of BBr3.The effect of different factors on isomer composition, yield, and enantiomeric purity of the compoundsobtained was investigated. Kovatch indices were determined and boiling points were estimated with the use of gas-liquid chromatography.

引用

页码：217 / 222

页数：5

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