Copper nanoparticles doped in wrinkled fibrous nanosilica as an efficient catalyst for the synthesis of 1,4-disubstituted 1,2,3-triazole in aqueous solution

被引:6
|
作者
Anvari, Mahsa [1 ]
Shadjou, Nasrin [1 ]
机构
[1] Urmia Univ, Fac Sci & Chem, Dept Nanotechnol, Orumiyeh, Iran
来源
MONATSHEFTE FUR CHEMIE | 2021年 / 152卷 / 10期
关键词
Aqueous solution process; Heterogeneous catalyst; Advanced nanomaterials; Dendritic fibrous nanosilica; Nanoreactor; AZIDE-ALKYNE CYCLOADDITION; ONE-POT SYNTHESIS; MAGNETIC NANOPARTICLES; TERMINAL ALKYNES; CLICK SYNTHESIS; BORONIC ACIDS; SODIUM-AZIDE; COMPLEX; KCC-1; WATER;
D O I
10.1007/s00706-021-02829-0
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A one-pot, highly efficient procedure was reported for the synthesis of 1,4-disubstituted 1,2,3-triazoles in water as a green solvent using Cu@KCC-1-NH-CS2 as a novel nanoreactor. Different methods such as Fourier transform infrared spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and adsorption/desorption analysis (BET equation) have been used for the characterization of engineered nanocatalyst. High surface area (133 m(2) g(-1)) and porous structure of the nanocatalyst, excellent catalytic performance in ecofriendly and green solvent with very short reaction times (5-20 min), easy work up, no use of toxic solvents, and suitable reusability of the catalyst are advantages of this presented work. Graphic abstract
引用
收藏
页码:1277 / 1284
页数:8
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