Synthesis and structure of iridium complexes [Ph3PR][trans-IrCl4(DMSO)2]

被引：3

作者：

Sharutin, V. V. ^{[1
]}

Sharutina, O. K. ^{[1
]}

Senchurin, V. S. ^{[1
]}

Somov, N. V. ^{[1
]}

机构：

[1] Natl Res South Ural State Univ, Chelyabinsk 454080, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 03期

关键词：

ionic iridium complexes; dimethyl sulfoxide; X-ray diffraction analysis;

D O I：

10.1134/S1070363215030184

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of sodium chloroiridate with acetonyl-, cyanomethyl-, and 2-butenyltriphenylphosphonium chloride in dimethyl sulfoxide was used to synthesize ionic iridium complexes [Ph3PR][trans-IrCl4(DMSO)(2)] (R = CH2C(O)Me, CH2CN, CH2CH=CHMe). The phosphorus atoms in the [Ph3RP](+) cations have a slightly distorted tetrahedral coordination. The dimethyl sulfoxide ligand in the octahedral anions [trans-IrCl4(DMSO)(2)] is coordinated to metal via sulfur atoms.

引用

页码：634 / 639

页数：6

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