Synthesis and structure of iridium complexes [Ph3PR][trans-IrCl4(DMSO)2]

被引：3
|
作者：
Sharutin, V. V. [1 ]
Sharutina, O. K. [1 ]
Senchurin, V. S. [1 ]
Somov, N. V. [1 ]
机构：
[1] Natl Res South Ural State Univ, Chelyabinsk 454080, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 03期
关键词：
ionic iridium complexes; dimethyl sulfoxide; X-ray diffraction analysis;
D O I：
10.1134/S1070363215030184
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of sodium chloroiridate with acetonyl-, cyanomethyl-, and 2-butenyltriphenylphosphonium chloride in dimethyl sulfoxide was used to synthesize ionic iridium complexes [Ph3PR][trans-IrCl4(DMSO)(2)] (R = CH2C(O)Me, CH2CN, CH2CH=CHMe). The phosphorus atoms in the [Ph3RP](+) cations have a slightly distorted tetrahedral coordination. The dimethyl sulfoxide ligand in the octahedral anions [trans-IrCl4(DMSO)(2)] is coordinated to metal via sulfur atoms.
引用
收藏
页码：634 / 639
页数：6
相关论文
共 50 条
  • [31] Iridium complexes [p-Tol4Sb]+[p-Tol4Sb(DMSO)]+[IrBr6]2– and [p-Tol4Sb(DMSO)]+[IrBr4(DMSO)2]–: Synthesis and structure
    V. V. Sharutin
    O. K. Sharutina
    V. S. Senchurin
    N. V. Somov
    Russian Journal of Inorganic Chemistry, 2016, 61 : 969 - 974
  • [32] Zirconium Complexes [Ph3PR] sub arrange=stack 2 sup arrange= stack +[ZrCl6]2-, R = Et, CH2Ph, CH2C(O)OMe: Synthesis and Structure
    Sharutin, V. V.
    Sharutina, O. K.
    Lobanova, E. V.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2018, 63 (12) : 1558 - 1563
  • [33] Synthesis and structure of osmium complexes: [Ph3PR] 2 + [OsBr6]2- (R = cyclo-C3H5, n-C4H9, cyclo-C6H11, CH2C(O)Ph), [Ph3PPr] 2 + [OsBr6]2- a™ DMSO, and [Ph3P(CH2)3PPh3]2+[OsBr6]2- a™ DMSO
    Sharutin, V. V.
    Sharutina, O. K.
    Senchurin, V. S.
    Pel'kov, P. A.
    Kodess, M. I.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2017, 43 (02) : 97 - 105
  • [34] Iridium Complexes [p-Tol4Sb]+[p-Tol4Sb(DMSO)]+[IrBr6]2- and [p-Tol4Sb(DMSO)]+[IrBr4(DMSO)2]-: Synthesis and Structure
    Sharutin, V. V.
    Sharutina, O. K.
    Senchurin, V. S.
    Somov, N. V.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2016, 61 (08) : 969 - 974
  • [35] Synthesis and characterization of IrH2{Si(OTf)Ph(2)}(TFB)(PR(3)) (PR(3)=P(i)Pr3, PCy(3)): First base-stabilized silylene complexes of iridium
    Chen, WZ
    Edwards, AJ
    Esteruelas, MA
    Lahoz, FJ
    Olivan, M
    Oro, LA
    ORGANOMETALLICS, 1996, 15 (08) : 2185 - 2188
  • [36] DINUCLEAR COMPLEXES OF RHODIUM AND IRIDIUM WITH CYANIDE OR THIOCYANATE BRIDGES - MOLECULAR-STRUCTURE OF [(PME2PH)3CL2IR(MU-CN)IRCL2(PME2PH)3][CLO4]
    DEEMING, AJ
    PROUD, GP
    DAWES, HM
    HURSTHOUSE, MB
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (09): : 2475 - 2481
  • [37] Synthesis and structure of osmium complexes: [Ph3PR]2+[OsBr6]2– (R = cyclo-C3H5, n-C4H9, cyclo-C6H11, CH2C(O)Ph), [Ph3PPr]2+[OsBr6]2– ∙ DMSO, and [Ph3P(CH2)3PPh3]2+[OsBr6]2– ∙ DMSO
    V. V. Sharutin
    O. K. Sharutina
    V. S. Senchurin
    P. A. Pel’kov
    M. I. Kodess
    Russian Journal of Coordination Chemistry, 2017, 43 : 97 - 105
  • [38] Structure and Synthesis of Dihalodicyanoaurate Complexes [Ph3PR][Au(CN)2Hal2] (Hal = Cl, R = Me, СH2Ph; Hal = Br, R = cyclo-C6H11; Hal = I, R = Ph)
    D. P. Shevchenko
    A. E. Khabina
    Russian Journal of Coordination Chemistry, 2023, 49 : 110 - 116
  • [39] Synthesis and Structure of Gold Complexes [Ph3PR][Au(CN)2Cl2] (R = CH2CH=CHCH3, CH2CN) and Ph3PC(H)(CN)Au(CN)2Cl
    D. P. Shevchenko
    A. E. Khabina
    V. V. Sharutin
    O. K. Sharutina
    V. S. Senchurin
    Russian Journal of Coordination Chemistry, 2022, 48 : 26 - 32
  • [40] Novel trialkylstibane iridium(I) and iridium(III) complexes including the X-ray crystal structure of five-coordinate [IrCl(C2H4)(2)(SbiPr(3))(2)]
    Werner, H
    Ortmann, DA
    Gevert, O
    CHEMISCHE BERICHTE, 1996, 129 (04) : 411 - 417
12345