Synthesis and structure of iridium complexes [Ph3PR][trans-IrCl4(DMSO)2]

被引：3
|
作者：
Sharutin, V. V. [1 ]
Sharutina, O. K. [1 ]
Senchurin, V. S. [1 ]
Somov, N. V. [1 ]
机构：
[1] Natl Res South Ural State Univ, Chelyabinsk 454080, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 03期
关键词：
ionic iridium complexes; dimethyl sulfoxide; X-ray diffraction analysis;
D O I：
10.1134/S1070363215030184
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of sodium chloroiridate with acetonyl-, cyanomethyl-, and 2-butenyltriphenylphosphonium chloride in dimethyl sulfoxide was used to synthesize ionic iridium complexes [Ph3PR][trans-IrCl4(DMSO)(2)] (R = CH2C(O)Me, CH2CN, CH2CH=CHMe). The phosphorus atoms in the [Ph3RP](+) cations have a slightly distorted tetrahedral coordination. The dimethyl sulfoxide ligand in the octahedral anions [trans-IrCl4(DMSO)(2)] is coordinated to metal via sulfur atoms.
引用
收藏
页码：634 / 639
页数：6
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