Direct cross-coupling of aryl alkynyliodines with arylsulfinic acids leading to alkynyl sulfones under catalyst-free conditions

被引：14

作者：

Wang, Leilei ^{[1
]}

Wei, Wei ^{[1
,2
]}

Yang, Daoshan ^{[1
]}

Cui, Huanhuan ^{[1
]}

Yue, Huilan ^{[2
]}

Wang, Hua ^{[1
]}

机构：

[1] Qufu Normal Univ, Inst Med & Mat Appl Technol, Sch Chem & Chem Engn, Key Lab Pharmaceut Intermediates & Anal Nat Med, Qufu 273165, Shandong, Peoples R China

[2] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China

来源：

TETRAHEDRON LETTERS | 2017年 / 58卷 / 51期

基金：

中国国家自然科学基金;

关键词：

Alkynyliodines; Sulfinic acids; Alkynyl sulfones; Additive-free; Catalyst-free; ONE-POT; HIGHLY EFFICIENT; SULFINIC ACIDS; CYCLOADDITIONS; SULFONYLATION; SUBSTITUTION; DIOXYGEN; ALKENES; DESIGN; AMINES;

D O I：

10.1016/j.tetlet.2017.11.029

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile and efficient one-pot method has been developed for the construction of alkynyl sulfones via direct cross-coupling reaction of aryl alkynyliodines and arylsulfinic acids. The present transformation could be accomplished under catalyst- and additive-free conditions, providing a series of alkynyl sulfones in moderate to good yields with favorable functional group tolerance. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：4799 / 4802

页数：4

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