Direct cross-coupling of aryl alkynyliodines with arylsulfinic acids leading to alkynyl sulfones under catalyst-free conditions

被引：14
|
作者：
Wang, Leilei [1 ]
Wei, Wei [1 ,2 ]
Yang, Daoshan [1 ]
Cui, Huanhuan [1 ]
Yue, Huilan [2 ]
Wang, Hua [1 ]
机构：
[1] Qufu Normal Univ, Inst Med & Mat Appl Technol, Sch Chem & Chem Engn, Key Lab Pharmaceut Intermediates & Anal Nat Med, Qufu 273165, Shandong, Peoples R China
[2] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China
来源：
TETRAHEDRON LETTERS | 2017年 / 58卷 / 51期
基金：
中国国家自然科学基金;
关键词：
Alkynyliodines; Sulfinic acids; Alkynyl sulfones; Additive-free; Catalyst-free; ONE-POT; HIGHLY EFFICIENT; SULFINIC ACIDS; CYCLOADDITIONS; SULFONYLATION; SUBSTITUTION; DIOXYGEN; ALKENES; DESIGN; AMINES;
D O I：
10.1016/j.tetlet.2017.11.029
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A facile and efficient one-pot method has been developed for the construction of alkynyl sulfones via direct cross-coupling reaction of aryl alkynyliodines and arylsulfinic acids. The present transformation could be accomplished under catalyst- and additive-free conditions, providing a series of alkynyl sulfones in moderate to good yields with favorable functional group tolerance. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4799 / 4802
页数：4
相关论文
共 50 条
  • [21] A convenient palladium/ligand catalyst for Suzuki cross-coupling reactions of arylboronic acids and aryl chlorides
    Bei, XH
    Crevier, T
    Guram, AS
    Jandeleit, B
    Powers, TS
    Turner, HW
    Uno, T
    Weinberg, WH
    TETRAHEDRON LETTERS, 1999, 40 (20) : 3855 - 3858
  • [22] Pd/MgO: A Recyclable, Ligand-free Heterogeneous Catalyst for Decarboxylative Cross-Coupling of Arene Carboxylic Acids with Aryl Halides
    Li Zhaohao
    Chen Jing
    Su Weiping
    Hong Maochun
    ACTA CHIMICA SINICA, 2014, 72 (05) : 552 - 556
  • [23] Direct C-H arylation of quinoxalinones with aryl acylperoxides under catalyst-free condition
    Chen, Bajin
    Wang, Shengpeng
    Song, Jinxing
    Wang, Xiaojun
    Yu, Bencheng
    Yang, Xiaobo
    TETRAHEDRON LETTERS, 2021, 62
  • [24] OXIDATIVE COUPLING OF O-PHENYLENEDIAMINE WITH ARYLMETHYLAMINES TO SYNTHESIZE ARYL-SUBSTITUTED BENZIMIDAZOLES UNDER CATALYST-FREE AND SOLVENT-FREE CONDITIONS
    Yu, Jiatao
    Lu, Ming
    SYNTHETIC COMMUNICATIONS, 2014, 44 (17) : 2520 - 2528
  • [25] Efficient Nickel Precatalysts for Suzuki-Miyaura Cross-Coupling of Aryl Chlorides and Arylboronic Acids Under Mild Conditions
    John, Morgan E.
    Nutt, Michael J.
    Offer, Josephine E.
    Duczynski, Jeremy A.
    Yamazaki, Ken
    Miura, Tomoya
    Moggach, Stephen A.
    Koutsantonis, George A.
    Dorta, Reto
    Stewart, Scott G.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2025,
  • [26] Catalyst-free diazo cross-coupling to access useful 3(2H)-furanone derivatives
    Sasane, Amit Vijay
    Liu, Rai-Shung
    CHEMICAL COMMUNICATIONS, 2023, 59 (08) : 1086 - 1089
  • [27] Recyclable Heterogeneous Iron Catalyst for C-N Cross-Coupling under Ligand-Free Conditions
    Swapna, K.
    Kumar, A. Vijay
    Reddy, V. Prakash
    Rao, K. Rama
    JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (19): : 7514 - 7517
  • [28] Catalyst-free benzylic C(sp3)-H cross-coupling with organotrifluoroborates enabled by electrochemistry
    Li, Chao
    Ding, Ran
    Guo, Heng-Yi
    Xia, Shuang
    Shu, Lei
    Wang, Pei-Long
    Li, Hongji
    GREEN CHEMISTRY, 2022, 24 (20) : 7883 - 7888
  • [29] An oxidant- and catalyst-free electrooxidative cross-coupling approach to 3-tetrahydroisoquinoline substituted coumarins
    Kong, Yanyan
    Kim, Jung Keun
    Li, Yabo
    Zhang, Jianye
    Huang, Mengmeng
    Wu, Yangjie
    GREEN CHEMISTRY, 2021, 23 (03) : 1274 - 1279
  • [30] A novel zinc-catalyzed Suzuki-type cross-coupling reaction of aryl boronic acids with alkynyl bromides
    Krishnan, K. Keerthi
    Saranya, Salim
    Rohit, K. R.
    Anilkumar, Gopinathan
    JOURNAL OF CATALYSIS, 2019, 372 : 266 - 271
12345