Catalyst controlled remote C-H activation of 8-aminoquinolines with NFSI for C-N versus C-F coupling

被引：4

作者：

Zheng, Kai ^{[1
]}

Zhou, Enmu ^{[1
]}

Zhang, Letian ^{[1
]}

Zhang, Lixi ^{[1
]}

Yu, Wenbo ^{[2
]}

Xu, Hao ^{[1
]}

Shen, Chao ^{[1
]}

机构：

[1] Zhejiang Shuren Univ, Coll Biol & Environm Engn, Hangzhou 310015, Peoples R China

[2] Hangzhou Vocat & Tech Coll, Linjiang Coll, Hangzhou 310018, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2021年 / 158卷

基金：

中国国家自然科学基金;

关键词：

Catalyst controlled; C-N coupling; C-F coupling; Quinoline; Heterogeneous; AMINATION; ALKENYLATION; FLUORINATION; QUINOLINES;

D O I：

10.1016/j.catcom.2021.106336

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A catalyst-controlled selective functionalization of 8-aminoquinolines with N-fluorobenzenesulfonimide (NFSI) has been developed. The use of GTP-Cu catalysts leads to C-N coupling products and whereas the C-F coupling reaction is dominant for GPT-Ni catalysis. Importantly, the GPT-Cu and GPT-Ni catalysts exhibit good catalytic activity and selectivity for C-N or C-F coupling reaction. In addition, it was found that both catalysts still have good activity for coupling reaction after fifth recycle experiment.

引用

页数：8

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