Luminescent Ag(I) scorpionates based on tris(2-pyridyl)phosphine oxide: Synthesis and cytotoxic activity evaluation

被引：24
|
作者：
Artem'ev, Alexander V. [1 ]
Eremina, Julia A. [1 ,2 ]
Lider, Elizaveta V. [1 ,2 ]
Antonova, Olga V. [1 ]
Vorontsova, Elena V. [3 ]
Bagryanskaya, Irina Yu. [2 ,4 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, 3 Akad Lavrentiev Ave, Novosibirsk 630090, Russia
[2] Natl Res Univ, Novosibirsk State Univ, Dept Nat Sci, 2 Pirogova Str, Novosibirsk 630090, Russia
[3] Inst Mol Biol & Biophys, 2-12 Timakova St, Novosibirsk 630117, Russia
[4] Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, 9 Akad Lavrentiev Ave, Novosibirsk 630090, Russia
来源：
POLYHEDRON | 2017年 / 138卷
基金：
俄罗斯基础研究基金会;
关键词：
Silver; Scorpionates; Luminescence; Cytotoxic activity; Tris(2-pyridyl)phosphine oxide; UNSUPPORTED SILVER-GERMANIUM; CATALYZED CARBENE INSERTION; ANTIMICROBIAL PROPERTIES; ETHYLENE COMPLEXES; ADDUCTS; LIGANDS; TRIS(PYRAZOLYL)BORATE; CARBONYL; COPPER; DERIVATIVES;
D O I：
10.1016/j.poly.2017.09.041
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
First representatives of Ag(I) scorpionates bearing tris(2-pyridyl)phosphine oxide (Py3P=O), viz. [Ag (Py3P=O)(PPh3)]BE4 (1) and [Ag(Py3P=O)(PPh3)]CIO4 (2), have been synthesized and structurally characterized. X-ray diffraction analysis reveals that the silver atom of 1 is coordinated by Py3P=O and Ph3P ligands in N,N',N"-tripodal and P-monodentate fashions, respectively. The both complexes exhibit significant cytotoxic activity (IC50 being from 11 to 14 mu M) screened in vitro against human larynx carcinoma (Hep-2) cell lines. The luminescent proprieties of the prepared scorpionates are also discussed. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：218 / 224
页数：7
相关论文
共 50 条
  • [41] Synthesis, characterization, and reactivity of a ruthenium(II) N,N',N''-tris(2-pyridyl)phosphine complex. X-ray analysis of RuCl2(PPh(3))(Ppy(3)) (py equals 2-pyridyl)
    Schutte, RP
    Rettig, SJ
    James, BR
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1996, 74 (11): : 2064 - 2072
  • [42] CuI-Based Coordination Polymer Assembled from a 2-Pyridyl Sulfide Ligand: Synthesis and Luminescent Properties
    Artem'ev, A. V.
    Rakhmanova, M. I.
    Samsonenko, D. G.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 60 (04) : 617 - 622
  • [43] COORDINATION OF BIS(2-PYRIDYL)PHOSPHINIC ACID AS A TRIDENTATE LIGAND - CRYSTAL-STRUCTURE OF THE (BIS(2-PYRIDYL)PHOSPHINATO)(TRIS(2-PYRIDYL)-PHOSPHINE OXIDE)RUTHENIUM(II) CATION, [RU(PY2P(O)O)(PY3PO)]BF4.2H2O
    KEENE, FR
    STEPHENSON, PJ
    TIEKINK, ERT
    INORGANICA CHIMICA ACTA, 1991, 187 (02) : 217 - 220
  • [44] CuI COMPLEXES BASED ON DI(2-PYRIDYL) (2-AROYLETHENYL)PHOSPHINE OXIDES: SYNTHESIS, STRUCTURE, AND DARK RED PHOTOLUMINESCENCE
    S. N. Arbuzova
    S. I. Verkhoturova
    T. N. Borodina
    A. V. Artem΄ev
    Journal of Structural Chemistry, 2022, 63 : 1383 - 1389
  • [45] CuI COMPLEXES BASED ON DI(2-PYRIDYL) (2-AROYLETHENYL)PHOSPHINE OXIDES: SYNTHESIS, STRUCTURE, AND DARK RED PHOTOLUMINESCENCE
    Arbuzova, S. N.
    Verkhoturova, S., I
    Borodina, T. N.
    Artem'ev, A., V
    JOURNAL OF STRUCTURAL CHEMISTRY, 2022, 63 (09) : 1383 - 1389
  • [46] Synthesis and chemistry of tris(2-pyridyl)phosphine and bis(2-pyridyl)phenylphosphine complexes of mercury(II) X (X = Br, Cl) and X-ray crystal structural determination of [HgBr2(PPh(2-py)2)2]
    Kharat, Ali Nemati
    Jahromi, Bahareh Tamaddoni
    Bakhoda, Abolghasem
    Abbasi, Alireza
    JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (21) : 3783 - 3791
  • [47] Tris(2-pyridyl)phosphine oxide:: how C-H•••O and C-H•••N interactions can affect crystal packing efficiency
    Bowen, RJ
    Fernandes, MA
    Gitari, PW
    Layh, M
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2004, 60 : O258 - O260
  • [48] "Marking" the Nitrogen Atoms of Phenyl-(2-pyridyl)-(3-pyridyl)-(4-pyridyl)-methane. Synthesis and Absolute Configuration of the Corresponding Tris(pyridine N-oxide)
    Matsumoto, Kouzou
    Miki, Kaori
    Inagaki, Takuya
    Nehira, Tatsuo
    Pescitelli, Gennaro
    Hirao, Yasukazu
    Kurata, Hiroyuki
    Kawase, Takeshi
    Kubo, Takashi
    CHIRALITY, 2011, 23 (07) : 543 - 548
  • [49] Coordination chemistry of the Janus-head ligand tris(2-pyridyl)phosphine [P(py)3] and its oxide with late first row transition metal nitrates
    Pericic, Danijel J.
    Dougherty, William G.
    Piro, Nicholas A.
    Kassel, W. Scott
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [50] Organic-inorganic hybrid iodobismuthate, [Bi(L)4(H2O)]Bi3I12, based on tris(2-pyridyl)phosphine oxide (L): Synthesis, structure and air-oxidation into [Bi(L)4]2[Bi4I16(I3)2]
    Artem'ev, Alexander, V
    Samsonenko, Denis G.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2018, 93 : 47 - 51
12345