Facile and chemo-selective synthesis of tertiary alkyl isothiocyanates from alcohols

被引:17
|
作者
Miyake, Hideyoshi [1 ]
Nakao, Yuichi [1 ]
Sasaki, Mitsuru [1 ]
机构
[1] Kobe Univ, Grad Sch Agr Sci, Kobe, Hyogo 6578501, Japan
关键词
D O I
10.1016/j.tet.2007.08.014
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
When tert-alcohols were treated with ( COOH) 2 and NaSCN in the presence of iodine, tertiary alkyl isothiocyanates were obtained in good yield, whereas the corresponding thiocyanates were obtained in low yield in the absence of iodine. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:10433 / 10436
页数:4
相关论文
共 50 条
  • [1] Facile water mediated chemo-selective synthesis of anilines from nitroarenes using triethylammonium formate
    Sridhara, M. B.
    Srinivasa, G. R.
    Gowda, D. Channe
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2006, 45 (05): : 1304 - 1307
  • [2] Visible light mediated chemo-selective oxidation of benzylic alcohols
    Devari, Shekaraiah
    Rizvi, Masood Ahmad
    Shah, Bhahwal Ali
    TETRAHEDRON LETTERS, 2016, 57 (30) : 3294 - 3297
  • [3] CHELATION-CONTROLLED CHEMO-SELECTIVE, REGIO-SELECTIVE AND ENANTIO-SELECTIVE SYNTHESIS OF HOMOALLYLIC ALCOHOLS
    CALO, V
    FIANDANESE, V
    NACCI, A
    SCILIMATI, A
    TETRAHEDRON, 1994, 50 (24) : 7283 - 7292
  • [4] Saccharomyces cerevisiae (Baker?s Yeast) catalyzed efficient and facile chemo-selective synthesis of aldimines
    Kauser, Samreen
    Ullah, Qasim
    Arifuddin, Mohammed
    Khan, Salman Ahmad
    Rehman, Aram
    RESULTS IN CHEMISTRY, 2023, 5
  • [5] Highly efficient Au hollow nanosphere catalyzed chemo-selective oxidation of alcohols
    Sasidharan, Manickam
    Anandhakumar, Sundaramurthy
    Bhanja, Piyali
    Bhaumik, Asim
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2016, 411 : 87 - 94
  • [6] Chemo-selective oxidation of hydroxybenzyl alcohols with IBX in the presence of hemicucurbit[6] uril
    Cong, Hang
    Yamato, Takehiko
    Tao, Zhu
    NEW JOURNAL OF CHEMISTRY, 2013, 37 (11) : 3778 - 3783
  • [7] Facile and chemo-selective cleavages of allyl ethers utilizing tetrabutylammonium sulfate radical species
    Yang, SG
    Park, MY
    Kim, YH
    SYNLETT, 2002, (03) : 492 - 494
  • [8] Chemo-Selective Synthesis of Tetrazole-Containing Cyclopentenyl Phosphanylidene Dicarboxylates
    Ektefai, Zahra
    Marandi, Ghasem
    Marjani, Ahmad Poursattar
    Zamani, Asghar
    CHEMISTRYSELECT, 2019, 4 (31): : 9055 - 9057
  • [9] Nickel-catalyzed hydrogen-borrowing strategy: chemo-selective alkylation of nitriles with alcohols
    Bera, Sourajit
    Bera, Atanu
    Banerjee, Debasis
    CHEMICAL COMMUNICATIONS, 2020, 56 (50) : 6850 - 6853
  • [10] Ni-nanoparticles: A mild chemo-selective catalyst for synthesis of thioethers
    Saxena, Amit
    Kumar, Ajeet
    Mozumdar, Subho
    APPLIED CATALYSIS A-GENERAL, 2007, 317 (02) : 210 - 215