Cobalt(II)-Catalyzed Isocyanide Insertion Reaction with Sulfonyl Azides in Alcohols: Synthesis of Sulfonyl Isoureas

被引：30

作者：

Jiang, Tian ^{[1
,2
]}

Gu, Zheng-Yang ^{[1
,2
]}

Yin, Ling ^{[1
,2
,3
]}

Wang, Shun-Yi ^{[1
,2
]}

Ji, Shun-Jun ^{[1
,2
]}

机构：

[1] Soochow Univ, Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China

[2] Soochow Univ, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Suzhou 215123, Peoples R China

[3] Jining Univ, Dept Chem & Chem Engn, Qufu 273155, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 82卷 / 15期

基金：

中国国家自然科学基金;

关键词：

TERT-BUTYL ISOCYANIDE; NITROGEN-SOURCE; ORGANIC AZIDES; POLYSUBSTITUTED PYRROLES; CHEMOSELECTIVE SYNTHESIS; NITRENE TRANSFER; DOMINO REACTION; ARYL AZIDES; AMINATION; GUANIDINES;

D O I：

10.1021/acs.joc.7b01127

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Co(II)-catalyzed isocyanide insertion reaction with sulfonyl azides in alcohols to form sulfonyl isoureas via nitrene intermediate has been developed. This protocol provides a new, environmentally friendly, and simple strategy for the synthesis of sulfonyl isourea derivatives by employing a range of substrates under mild conditions.

引用

页码：7913 / 7919

页数：7

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