Cobalt(II)-Catalyzed Isocyanide Insertion Reaction with Sulfonyl Azides in Alcohols: Synthesis of Sulfonyl Isoureas

被引：30
|
作者：
Jiang, Tian [1 ,2 ]
Gu, Zheng-Yang [1 ,2 ]
Yin, Ling [1 ,2 ,3 ]
Wang, Shun-Yi [1 ,2 ]
Ji, Shun-Jun [1 ,2 ]
机构：
[1] Soochow Univ, Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
[2] Soochow Univ, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Suzhou 215123, Peoples R China
[3] Jining Univ, Dept Chem & Chem Engn, Qufu 273155, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 82卷 / 15期
基金：
中国国家自然科学基金;
关键词：
TERT-BUTYL ISOCYANIDE; NITROGEN-SOURCE; ORGANIC AZIDES; POLYSUBSTITUTED PYRROLES; CHEMOSELECTIVE SYNTHESIS; NITRENE TRANSFER; DOMINO REACTION; ARYL AZIDES; AMINATION; GUANIDINES;
D O I：
10.1021/acs.joc.7b01127
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A Co(II)-catalyzed isocyanide insertion reaction with sulfonyl azides in alcohols to form sulfonyl isoureas via nitrene intermediate has been developed. This protocol provides a new, environmentally friendly, and simple strategy for the synthesis of sulfonyl isourea derivatives by employing a range of substrates under mild conditions.
引用
收藏
页码：7913 / 7919
页数：7
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