Iridium-Catalyzed Oxidative Methyl Esterification of Primary Alcohols and Diols with Methanol

被引:88
|
作者
Yamamoto, Nobuyuki [1 ]
Obora, Yasushi [1 ]
Ishii, Yasutaka [1 ]
机构
[1] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, Osaka 5648680, Japan
来源
JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 08期
关键词
CARBOXYLIC-ACIDS; ESTERS; ALDEHYDES; EFFICIENT; TRANSFORMATION; DIMERIZATION; CONVERSION; DIOXIDE; TRIMETHYLSILYLDIAZOMETHANE; HYDROGENATION;
D O I
10.1021/jo2003264
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Oxidative methyl esterification of primary alcohols and diols with methanol was successfully achieved, using acetone as a hydrogen acceptor, under the influence of an iridium complex combined with 2-(methylamino)ethanol (MAE) as catalyst.
引用
收藏
页码:2937 / 2941
页数:5
相关论文
共 50 条
  • [41] Improved Catalysts for the Iridium-Catalyzed Asymmetric Isomerization of Primary Allylic Alcohols Based on Charton Analysis
    Mantilli, Luca
    Gerard, David
    Torche, Sonya
    Besnard, Celine
    Mazet, Clement
    CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (42) : 12736 - 12745
  • [42] Iridium-Catalyzed Coupling Reaction of Primary Alcohols with 2-Alkynes Leading to Hydroacylation Products
    Hatanaka, Shintaro
    Obora, Yasushi
    Ishii, Yasutaka
    CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (06) : 1883 - 1888
  • [43] Iridium-Catalyzed Asymmetric Allylic Substitution of Methyl Azaarenes
    Liu, Xi-Jia
    Zhang, Wen-Yun
    Zheng, Chao
    You, Shu-Li
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (20)
  • [44] Iridium-catalyzed Oppenauer oxidations of primary alcohols using acetone or 2-butanone as oxidant
    Suzuki, T
    Morita, K
    Tsuchida, M
    Hiroi, K
    JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (04): : 1601 - 1602
  • [45] Iridium-catalyzed methylation of indoles and pyrroles using methanol as feedstock
    Chen, Shu-Jie
    Lu, Guo-Ping
    Cai, Chun
    RSC ADVANCES, 2015, 5 (86): : 70329 - 70332
  • [46] Iridium-Catalyzed C-Alkylation of Methyl Group on N-Heteroaromatic Compounds using Alcohols
    Onoda, Mitsuki
    Fujita, Ken-ichi
    ORGANIC LETTERS, 2020, 22 (18) : 7295 - 7299
  • [47] Clean preparation of methyl esters in one-step oxidative esterification of primary alcohols catalyzed by supported gold nanoparticles
    Oliveira, Rafael L.
    Kiyohara, Pedro K.
    Rossi, Liane M.
    GREEN CHEMISTRY, 2009, 11 (09) : 1366 - 1370
  • [48] Iridium-Catalyzed Coupling Reaction of Primary Alcohols with 1-Aryl-1-propynes Leading to Secondary Homoallylic Alcohols
    Obora, Yasushi
    Hatanaka, Shintaro
    Ishii, Yasutaka
    ORGANIC LETTERS, 2009, 11 (15) : 3510 - 3513
  • [49] OXIDATIVE DEHYDROGENATION OF SECONDARY ALCOHOLS CATALYZED BY IRIDIUM
    THANH, LN
    KRAUS, M
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1973, 38 (10) : 2931 - 2937
  • [50] OPTIMIZATION OF THE PAPAIN CATALYZED ESTERIFICATION OF AMINO-ACIDS BY ALCOHOLS AND DIOLS
    CANTACUZENE, D
    GUERREIRO, C
    TETRAHEDRON, 1989, 45 (03) : 741 - 748