Iridium-Catalyzed Oxidative Methyl Esterification of Primary Alcohols and Diols with Methanol

被引：88
|
作者：
Yamamoto, Nobuyuki [1 ]
Obora, Yasushi [1 ]
Ishii, Yasutaka [1 ]
机构：
[1] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, Osaka 5648680, Japan
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 76卷 / 08期
关键词：
CARBOXYLIC-ACIDS; ESTERS; ALDEHYDES; EFFICIENT; TRANSFORMATION; DIMERIZATION; CONVERSION; DIOXIDE; TRIMETHYLSILYLDIAZOMETHANE; HYDROGENATION;
D O I：
10.1021/jo2003264
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Oxidative methyl esterification of primary alcohols and diols with methanol was successfully achieved, using acetone as a hydrogen acceptor, under the influence of an iridium complex combined with 2-(methylamino)ethanol (MAE) as catalyst.
引用
收藏
页码：2937 / 2941
页数：5
相关论文
共 50 条
  • [21] Iridium-Catalyzed Synthesis of ω-Hydroxy Homoallylic Alcohols
    Obora, Yasushi
    Sawaguchi, Takuya
    Tsubakimoto, Keiko
    Yoshida, Hiroshi
    Ogawa, Shinji
    Hatanaka, Shintaro
    SYNTHESIS-STUTTGART, 2013, 45 (15): : 2115 - 2119
  • [22] Enantio- and Regioselective Iridium-Catalyzed Allylic Esterification
    Qu, Jianping
    Rossberg, Lydia
    Helmchen, Guenter
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (04) : 1272 - 1275
  • [23] IRIDIUM-CATALYZED N-HETEROCYCLIZATION OF PRIMARY AMINES WITH DIOLS: N-BENZYLPIPERIDINE
    Fujita, Ken-ichi
    Enoki, Youichiro
    Yamaguchi, Ryohei
    ORGANIC SYNTHESES, 2006, 83 : 217 - +
  • [24] Iridium-catalyzed addition of methanol to internal alkynes
    Konkol, Marcin
    Schmidt, Harry
    Steinborn, Dirk
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 261 (02) : 301 - 305
  • [25] Iridium-catalyzed addition of methanol to terminal alkynes
    Konkol, Marcin
    Schmidt, Harry
    Steinborn, Dirk
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 269 (1-2) : 119 - 124
  • [26] Experimental and Theoretical Mechanistic Investigation of the Iridium-Catalyzed Dehydrogenative Decarbonylation of Primary Alcohols
    Olsen, Esben P. K.
    Singh, Thishana
    Harris, Pernille
    Andersson, Pher G.
    Madsen, Robert
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (02) : 834 - 842
  • [27] Structure-Activity Relationship in the Iridium-Catalyzed Isomerization of Primary Allylic Alcohols
    Mantilli, Luca
    Gerard, David
    Besnard, Celine
    Mazet, Clement
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (20) : 3320 - 3330
  • [28] Iridium-catalyzed isomerization of primary allylic alcohols under mild reaction conditions
    Mantilli, Luca
    Mazet, Clement
    TETRAHEDRON LETTERS, 2009, 50 (28) : 4141 - 4144
  • [29] Iridium-Catalyzed Decarboxylative N-Alkylation of α-Amino Acids with Primary Alcohols
    Wu, Jiashou
    Jiang, Huajiang
    Chen, Dingben
    Shen, Jianfen
    Zhao, Datong
    Xiang, Jing
    Zhou, Qizhong
    SYNLETT, 2014, 25 (04) : 539 - 542
  • [30] Iridium-catalyzed selective α-methylation of ketones with methanol
    Ogawa, Shinji
    Obora, Yasushi
    CHEMICAL COMMUNICATIONS, 2014, 50 (19) : 2491 - 2493
12345