Alternative Demetalation Method for Cu(I)-Phenanthroline-Based Catenanes and Rotaxanes

被引：35
|
作者：
Megiatto, Jackson D., Jr. [1 ]
Schuster, David I. [1 ]
机构：
[1] NYU, Dept Chem, New York, NY 10003 USA
来源：
ORGANIC LETTERS | 2011年 / 13卷 / 07期
基金：
美国国家卫生研究院; 美国国家科学基金会;
关键词：
INTERLOCKED MACROCYCLIC LIGANDS; CONVERGENT SYNTHESIS; PHOTOINDUCED PROCESSES; COORDINATION-COMPOUNDS; TEMPLATED SYNTHESIS; COMPLEXES; PHOTOPHYSICS; METATHESIS; COPPER(I); PORPHYRIN;
D O I：
10.1021/ol200304d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new and less hazardous procedure for demetalation of Cu(I)-phenanthroline-based interlocked molecules, using aqueous MOH rather than toxic KCN, has been developed. The conditions are compatible with materials containing nucleophile-sensitive appended groups such as C-60, and coordinating moieties such as zinc(II)-porphyrins.
引用
收藏
页码：1808 / 1811
页数：4
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