Alternative Demetalation Method for Cu(I)-Phenanthroline-Based Catenanes and Rotaxanes

被引：35
|
作者：
Megiatto, Jackson D., Jr. [1 ]
Schuster, David I. [1 ]
机构：
[1] NYU, Dept Chem, New York, NY 10003 USA
来源：
ORGANIC LETTERS | 2011年 / 13卷 / 07期
基金：
美国国家卫生研究院; 美国国家科学基金会;
关键词：
INTERLOCKED MACROCYCLIC LIGANDS; CONVERGENT SYNTHESIS; PHOTOINDUCED PROCESSES; COORDINATION-COMPOUNDS; TEMPLATED SYNTHESIS; COMPLEXES; PHOTOPHYSICS; METATHESIS; COPPER(I); PORPHYRIN;
D O I：
10.1021/ol200304d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new and less hazardous procedure for demetalation of Cu(I)-phenanthroline-based interlocked molecules, using aqueous MOH rather than toxic KCN, has been developed. The conditions are compatible with materials containing nucleophile-sensitive appended groups such as C-60, and coordinating moieties such as zinc(II)-porphyrins.
引用
收藏
页码：1808 / 1811
页数：4
相关论文
共 42 条
  • [1] Alternative routes to phenanthroline-based diones
    Pacheco, Kimberly
    Covelli, Daniel
    Bresch, Cayla
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [2] Chemical modification of amide-based catenanes and rotaxanes I.: Synthesis of secondary amine [2]catenanes and [2]rotaxanes by the borane reduction of secondary amide [2]catenanes and [2]rotaxanes and mobility of their components
    Furusho, Y
    Shoji, J
    Watanabe, N
    Kihara, N
    Adachi, T
    Takata, T
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2001, 74 (01) : 139 - 147
  • [3] Hybrid Bis-Histidine Phenanthroline-Based Ligands to Lessen Aβ-Bound Cu ROS Production: An Illustration of Cu(I) Significance
    Drommi, Marielle
    Rulmont, Clement
    Esmieu, Charlene
    Hureau, Christelle
    MOLECULES, 2021, 26 (24):
  • [4] A silver(I) coordinated phenanthroline-based polymer with high ethylene/ethane adsorption selectivity
    Yu, Chao
    Cowan, Matthew G.
    Noble, Richard D.
    Zhang, Wei
    CHEMICAL COMMUNICATIONS, 2014, 50 (43) : 5745 - 5747
  • [5] Feasible fabrication of o -phenanthroline-based polymer adsorbent for selective capture of aqueous Ag(I)
    Ding, Xuan
    Yu, Wanjun
    Sheng, Xin
    Shi, Hui
    You, Deng
    Peng, Mingming
    Shao, Penghui
    Yang, Liming
    Liu, Lingling
    Luo, Xubiao
    CHINESE CHEMICAL LETTERS, 2023, 34 (03)
  • [6] Bright or Dark: Unexpected Photocatalytic Behavior of Closely Related Phenanthroline-based Copper(I) Photosensitizers
    Doettinger, Florian
    Obermeier, Martin
    Caliskanyuerek, Volkan
    Burmeister, Lars E.
    Kleeberg, Christian
    Karnahl, Michael
    Schwalbe, Matthias
    Tschierlei, Stefanie
    CHEMCATCHEM, 2023, 15 (16)
  • [7] Topo I inhibition, DNA photocleavage, Molecular docking and cytotoxicities of two new phenanthroline-based ruthenium complexes
    Liu, Xue-Wen
    Tang, Yu-Cai
    Liu, Ning-Yi
    Deng, Yuan-Qing
    Wang, Shan
    Liu, Ting
    Chen, Yuan-Dao
    Lu, Ji-Lin
    APPLIED ORGANOMETALLIC CHEMISTRY, 2020, 34 (02)
  • [8] Discoveries from a phenanthroline-based dynamic combinatorial library: catenane from a copper(I) or copper(II) template?
    Tong, King-Lung
    Yee, Chi-Chung
    Tse, Yuen Cheong
    Au-Yeung, Ho Yu
    INORGANIC CHEMISTRY FRONTIERS, 2016, 3 (03): : 348 - 353
  • [9] Copper(I) Photoredox Catalysts Bearing Tetradentate Phenanthroline-Based Ligands: Understanding the Interplay between Structure and Function
    Olding, Angus
    Cameron, Lee
    Pham, Le Nhan
    Shephard, James P.
    Lucas, Nigel T.
    Moggach, Stephen A.
    Massi, Massimiliano
    Connell, Timothy U.
    Ho, Curtis C.
    Coote, Michelle L.
    Bissember, Alex C.
    ACS CATALYSIS, 2025, 15 (05): : 3731 - 3740
  • [10] Radical Hydrodehalogenation of Aryl Halides with H2 Catalyzed by a Phenanthroline-Based PNNP Cobalt(I) Complex
    Jheng, Nai-Yuan
    Ishizaka, Yusuke
    Naganawa, Yuki
    Minami, Yasunori
    Sekiguchi, Akira
    Iizuka, Kosuke
    Nakajima, Yumiko
    ACS CATALYSIS, 2022, 12 (04) : 2320 - 2329
12345