Supercritical CO2:: an effective medium for the chemo-enzymatic synthesis of block copolymers?

被引:25
|
作者
Villarroya, Silvia
Thurecht, Kristofer J.
Heise, Andreas
Howdle, Steven M.
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[2] DSM Res & Patents, NL-6160 MD Geleen, Netherlands
关键词
D O I
10.1039/b701128h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this review, we describe the combination of enzymatic polymerisation and controlled free radical polymerisation in supercritical carbon dioxide. This combination facilitates the preparation of a range of block and graft copolymers, some of which cannot easily be obtained by conventional polymer synthesis. Biocatalysis in polymer science provides significant new opportunities and will open up a very broad range of new polymeric materials.
引用
收藏
页码:3805 / 3813
页数:9
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